Dimanganese decacarbonyl/2-cyanoprop-2-yl-1-dithionaphthalate: toward sunlight induced RAFT polymerization of MMA

2014 ◽  
Vol 5 (16) ◽  
pp. 4641-4648 ◽  
Author(s):  
Xuelang Miao ◽  
Jiajia Li ◽  
Zhengbiao Zhang ◽  
Zhenping Cheng ◽  
Wei Zhang ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Controlled Radical Polymerization ◽  
Moderate Temperature ◽  
Sunlight Irradiation ◽  
Green Led ◽  
Dimanganese Decacarbonyl

Methyl methacrylate was polymerized in the presence of dimanganese decacarbonyl [Mn2(CO)10]/2-cyanoprop-2-yl-1-dithionaphthalate (CPDN) via a photo-induced controlled radical polymerization under visible (green LED with λmax of 565 nm) or sunlight irradiation at a moderate temperature.

Organocatalytic PET-RAFT Polymerization with ppm of Organic Photocatalyst under Visible Light

2021 ◽  
Author(s):  
Qiang Ma ◽  
Xun Zhang ◽  
Yu Jiang ◽  
Junqiang Lin ◽  
Bernadette Graff ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Controlled Radical Polymerization ◽  
Polymerization Process ◽  
Light Control

The development of light-mediated controlled radical polymerization has benefited from the discovery of novel photocatalysts, which could allow a precise light control over the polymerization process and the production of...

scholarly journals Reversible addition fragmentation chain transfer polymerization - RAFT

2004 ◽  
Vol 58 (11) ◽  
pp. 514-520
Author(s):  
Milena Avramovic ◽  
Lynne Katsikas ◽  
Branko Dunjic ◽  
Ivanka Popovic
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
General Structure ◽  
Controlled Radical Polymerization ◽  
Molecular Structures ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

The fundamentals of controlled radical polymerization are presented in this review. The paper focuses on reversible addition fragmentation chain transfer (RAFT) polymerization. The mechanism and specifics of this type of polymerization are discussed, as are the possibilities of synthesizing complex macro-molecular structures. The synthesis and properties of RAFT agents, of the general structure Z-C(=S)-S-R, are presented.

Mechanism of the controlled radical polymerization of styrene and methyl methacrylate in the presence of dicyclopentadienyltitanium dichloride

2004 ◽  
Vol 18 (6) ◽  
pp. 271-276 ◽  
Author(s):  
Dmitry F. Grishin ◽  
Stanislav K. Ignatov ◽  
Alexander A. Shchepalov ◽  
Alexey G. Razuvaev
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization

Photoinduced controlled radical polymerization of methyl acrylate and vinyl acetate by xanthate

2018 ◽  
Vol 9 (21) ◽  
pp. 2897-2904 ◽  
Author(s):  
Jiajia Li ◽  
Xiangqiang Pan ◽  
Na Li ◽  
Jian Zhu ◽  
Xiulin Zhu
Keyword(s):  
Block Copolymer ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Raft Polymerization ◽  
Controlled Radical Polymerization

A block copolymer of PMA-b-PVAc was successfully synthesized using photo-induced RAFT polymerization with a xanthate.

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