Luminescent properties of Ag(i)/Cu(i) coordination polymers: crystal structures and high intensity luminescence of a PMMA-doped hybrid material based on a quinoline-2,3-dicarboxylic acid ligand

RSC Advances ◽  
2015 ◽  
Vol 5 (22) ◽  
pp. 17343-17353 ◽  
Author(s):  
Yang Song ◽  
Rui-Qing Fan ◽  
Hui-Jie Zhang ◽  
Zhi-Wei Liu ◽  
Xue-Tao Wang ◽  
...  

Preparation, characterization, crystal structure and different luminescent properties of Ag(i)/Cu(i) coordination polymers: stable blue emission, thermochromism and PMMA-doped hybrid material.

RSC Advances ◽  
2015 ◽  
Vol 5 (21) ◽  
pp. 16190-16198 ◽  
Author(s):  
Zhi-Hao Yan ◽  
Wen Wang ◽  
Liangliang Zhang ◽  
Xiaowei Zhang ◽  
Lei Wang ◽  
...  

Three new coordination polymers (CPs) based on H2ndc acid have been synthesized and structurally characterized. Three CPs exhibit structural diversity depending on different bis(imidazole) bridging ligands and center metal ions.


Author(s):  
Xianyu Huang ◽  
Daoliang Chen ◽  
Mingrui He ◽  
Jianfeng Li ◽  
Jiawei Huang ◽  
...  

Four novel coordination polymers (CPs) assembled with [2,2′-bifuran]-5,5′-dicarboxylic acid (H2L) and metal ions ZnII, CdIIor CoIIhave been successfully synthesized. Their molecular structures have been determined to be Zn(L)(H2O)2(1), [Zn(L)(DMF)]2(2), [Cd(L)(EtOH)(DMF)2]2(3) and Co(L)(H2O)4·(H2O)2(4) by crystallographic analysis. It is found that (2) exhibits a two-dimensional infinite framework, whereas the others exhibit a one-dimensional framework. Both (2) and (3) exhibit ligand-based emission which is blue-shifted compared with the emission from the H2Lligand. Time-resolved spectroscopic measurement reveals that the complexes exhibit a similar lifetime with that of the ligand, which confirms that the emission of the complexes originates from the ligand.


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