Coordination chemistry of mixed M(benzene)(cyclopendadienyl) sandwich complexes: electronic properties and bonding analysis

2016 ◽  
Vol 40 (3) ◽  
pp. 2554-2564 ◽  
Author(s):  
Saber-Mustapha Zendaoui ◽  
Bachir Zouchoune
Keyword(s):  
Coordination Chemistry ◽  
Electronic Properties ◽  
Spin State ◽  
Sandwich Complexes ◽  
Coordination Modes ◽  
Bonding Analysis ◽  
Iron Metal

Various coordination modes are adopted by the benzene and the cyclopentadienyl ring depending on the electron count of the iron metal and the spin state of the complex.

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: An investigation from the coordination modes to spectroscopic insights

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115068
Author(s):  
Isabelle K.V. Gonçalves ◽  
Willian X.C. Oliveira ◽  
Filipe B. de Almeida ◽  
Maria Vanda Marinho ◽  
Walace D. do Pim ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Coordination Modes

ChemInform Abstract: Tetradecker LM(C3B2)Co(C2B3)CoCp Sandwich Complexes (LM: Cp*Co, Cp*Rh, or (cymene)Ru). Designed Synthesis and Electronic Properties.

ChemInform ◽  
2010 ◽  
Vol 22 (15) ◽  
pp. no-no
Author(s):  
A. FESSENBECKER ◽  
M. D. ATTWOOD ◽  
R. N. GRIMES ◽  
M. STEPHAN ◽  
H. PRITZKOW ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Sandwich Complexes ◽  
Designed Synthesis

scholarly journals Coordination Chemistry of Anticrowns. Synthesis and Structures of Double-Decker Sandwich Complexes of the Three-Mercury Anticrown (o-C6F4Hg)3 with Halide Anions Containing and Not Containing Coordinated Dibromomethane Molecules

2016 ◽  
Vol 35 (13) ◽  
pp. 2197-2206 ◽  
Author(s):  
Kirill I. Tugashov ◽  
Dmitry A. Gribanyov ◽  
Fedor M. Dolgushin ◽  
Alexander F. Smol’yakov ◽  
Alexander S. Peregudov ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Sandwich Complexes ◽  
Halide Anions ◽  
Double Decker

scholarly journals Complexes of the tripodal phosphine ligands PhSi(XPPh2)3(X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2

2016 ◽  
Vol 45 (37) ◽  
pp. 14774-14788 ◽  
Author(s):  
Alicia Aloisi ◽  
Jean-Claude Berthet ◽  
Caroline Genre ◽  
Pierre Thuéry ◽  
Thibault Cantat
Keyword(s):  
Catalytic Activity ◽  
Coordination Chemistry ◽  
Electronic Properties ◽  
Phosphine Ligands ◽  
Phosphorus Ligands ◽  
The Impact

The coordination chemistry of Fe2+, Co2+and Cu+ions was explored with the ligands PhSi{CH2PPh2}3(1) and PhSi{OPPh2}3(2), so as to evaluate the impact of the electronic properties of the tripodal phosphorus ligands on the structure and reactivity of the corresponding complexes.

Cycloheptatrienyl Zirconium Sandwich Complexes with Lewis Basic Phospholyl Ligands (Phosphatrozircenes): Synthesis, Structure, Bonding and Coordination Chemistry

2011 ◽  
Vol 17 (22) ◽  
pp. 6118-6128 ◽  
Author(s):  
Andreas Glöckner ◽  
Thomas Bannenberg ◽  
Susanne Büschel ◽  
Constantin G. Daniliuc ◽  
Peter G. Jones ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Sandwich Complexes

Sterically Demanding, Sulfonated, Triarylphosphines: Application to Palladium-Catalyzed Cross-Coupling, Steric and Electronic Properties, and Coordination Chemistry

2008 ◽  
Vol 27 (4) ◽  
pp. 576-593 ◽  
Author(s):  
Lucas R. Moore ◽  
Elizabeth C. Western ◽  
Raluca Craciun ◽  
Jason M. Spruell ◽  
David A. Dixon ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Electronic Properties ◽  
Cross Coupling ◽  
Sterically Demanding ◽  
Palladium Catalyzed
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