Marriage of heavy main group elements with π-conjugated materials for optoelectronic applications

2016 ◽  
Vol 52 (61) ◽  
pp. 9485-9505 ◽  
Author(s):  
Sarah M. Parke ◽  
Michael P. Boone ◽  
Eric Rivard
Keyword(s):  
Recent Work ◽  
Main Group ◽  
The Novel ◽  
Inorganic Elements ◽  
Conjugated Materials ◽  
Main Group Elements ◽  
Optoelectronic Applications

This review showcases recent work devoted to placing heavy inorganic elements within π-conjugated frameworks and the novel properties that can arise.

Ladder π-Conjugated Materials with Main Group Elements

ChemInform ◽  
2006 ◽  
Vol 37 (36) ◽  
Author(s):  
Shigehiro Yamaguchi ◽  
Caihong Xu ◽  
Toshihiro Okamoto
Keyword(s):  
Main Group ◽  
Conjugated Materials ◽  
Main Group Elements

Metal-catalyzed routes to rings, chains, and macromolecules based on inorganic elements

2005 ◽  
Vol 77 (12) ◽  
pp. 1991-2002 ◽  
Author(s):  
Alexandra Bartole-Scott ◽  
Cory A. Jaska ◽  
Ian Manners
Keyword(s):  
Recent Work ◽  
Main Group ◽  
Inorganic Elements ◽  
Transition Elements ◽  
Metal Catalyzed

In this perspective article, some of our recent work directed at the development of new catalytic routes to rings, chains, and macromolecules based on main group and transition elements will be discussed.

Ladder π-Conjugated Materials Containing Main-Group Elements

2009 ◽  
Vol 4 (9) ◽  
pp. 1386-1400 ◽  
Author(s):  
Aiko Fukazawa ◽  
Shigehiro Yamaguchi
Keyword(s):  
Main Group ◽  
Conjugated Materials ◽  
Main Group Elements

F Perfluorohalogenoorgano Compounds of Main Group Elements

1987 ◽  
Author(s):  
Alois Haas ◽  
Dieter Koschel ◽  
Ulrich Niemann
Keyword(s):  
Main Group ◽  
Main Group Elements

To Bend or Not to Bend, the Dilemma of Multiple Bonds

2019 ◽  
Author(s):  
Michele Pizzocchero ◽  
Matteo Bonfanti ◽  
Rocco Martinazzo
Keyword(s):  
First Principles ◽  
2D Materials ◽  
Main Group ◽  
First Principles Calculations ◽  
Group 14 ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
Structural Distortions

The manuscript addresses the issue of the structural distortions occurring at multiple bonds between high main group elements, focusing on group 14. These distortions are known as trans-bending in silenes, disilenes and higher group analogues, and buckling in 2D materials likes silicene and germanene. A simple but correlated \sigma + \pi model is developed and validated with first-principles calculations, and used to explain the different behaviour of second- and higher- row elements.

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