Direct synthesis of doubly deprotonated, dearomatised lutidine PNP Cr and Zr pincer complexes based on isolated K and Li ligand transfer reagents

Double deprotonation of a hybrid bis(phosphino)picoline ligand yields lithium or potassium pincer salts with dearomatised lutidine backbones that afford unusual chromium and zirconium complexes by transmetallation.

Download Full-text

ChemInform Abstract: Direct Synthesis of Pyridines and Quinolines by Coupling of γ-Amino-alcohols with Secondary Alcohols Liberating H2Catalyzed by Ruthenium Pincer Complexes.

ChemInform ◽

10.1002/chin.201344154 ◽

2013 ◽

Vol 44 (44) ◽

pp. no-no

Author(s):

Dipankar Srimani ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Amino Alcohols ◽

Pincer Complexes ◽

Secondary Alcohols

Download Full-text

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

Angewandte Chemie ◽

10.1002/ange.201300574 ◽

2013 ◽

Vol 125 (14) ◽

pp. 4104-4107 ◽

Cited By ~ 68

Author(s):

Dipankar Srimani ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Pincer Complexes ◽

Secondary Alcohols ◽

Dehydrogenative Coupling

Download Full-text

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes

Angewandte Chemie International Edition ◽

10.1002/anie.201607742 ◽

2016 ◽

Vol 55 (46) ◽

pp. 14373-14377 ◽

Cited By ~ 98

Author(s):

Prosenjit Daw ◽

Subrata Chakraborty ◽

Jai Anand Garg ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Pincer Complexes ◽

Dehydrogenative Coupling

Download Full-text

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

Chemical Communications ◽

10.1039/c3cc43227k ◽

2013 ◽

Vol 49 (59) ◽

pp. 6632 ◽

Cited By ~ 115

Author(s):

Dipankar Srimani ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Amino Alcohols ◽

Pincer Complexes ◽

Secondary Alcohols

Download Full-text

Yttrate-Mediated Ligand Transfer and Direct Synthesis as a Route to Amidopalladium Complexes

Angewandte Chemie International Edition ◽

10.1002/(sici)1521-3773(19980403)37:6<832::aid-anie832>3.0.co;2-a ◽

1998 ◽

Vol 37 (6) ◽

pp. 832-835 ◽

Cited By ~ 41

Author(s):

Anke Spannenberg ◽

Perdita Arndt ◽

Rhett Kempe

Keyword(s):

Direct Synthesis ◽

Ligand Transfer

Download Full-text

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes

Angewandte Chemie ◽

10.1002/ange.201607742 ◽

2016 ◽

Vol 128 (46) ◽

pp. 14585-14589 ◽

Cited By ~ 28

Author(s):

Prosenjit Daw ◽

Subrata Chakraborty ◽

Jai Anand Garg ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Pincer Complexes ◽

Dehydrogenative Coupling

Download Full-text

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

Angewandte Chemie International Edition ◽

10.1002/anie.201300574 ◽

2013 ◽

Vol 52 (14) ◽

pp. 4012-4015 ◽

Cited By ~ 220

Author(s):

Dipankar Srimani ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Pincer Complexes ◽

Secondary Alcohols ◽

Dehydrogenative Coupling

Download Full-text

Efficient Direct Synthesis of Tropidinyl Titanium and Zirconium Complexes by Allylic CH-Activation of 8-Methyl-8-azabicyclo[3.2.1]oct-2-ene (Tropidine)

Organometallics ◽

10.1021/om0609564 ◽

2007 ◽

Vol 26 (3) ◽

pp. 761-764 ◽

Cited By ~ 7

Author(s):

Matthias Tamm ◽

Andreas Kunst ◽

Michael Stadler ◽

Eberhardt Herdtweck

Keyword(s):

Direct Synthesis ◽

Ch Activation ◽

Zirconium Complexes

Download Full-text

ChemInform Abstract: Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes.

ChemInform ◽

10.1002/chin.201335105 ◽

2013 ◽

Vol 44 (35) ◽

pp. no-no

Author(s):

Dipankar Srimani ◽

Yehoshoa Ben-David ◽

David Milstein

Keyword(s):

Direct Synthesis ◽

Pincer Complexes ◽

Secondary Alcohols ◽

Dehydrogenative Coupling

Download Full-text

Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene

Dalton Transactions ◽

10.1039/c6dt01149g ◽

2016 ◽

Vol 45 (27) ◽

pp. 11101-11108 ◽

Cited By ~ 15

Author(s):

Shi Jiang ◽

Samuel Quintero-Duque ◽

Thierry Roisnel ◽

Vincent Dorcet ◽

Mary Grellier ◽

...

Keyword(s):

Efficient Method ◽

Direct Synthesis ◽

Iron Carbonyl ◽

Pincer Complexes ◽

Hydride Complexes ◽

Iron Hydride

An efficient method based on the simple metalating reagent Fe(CO)5 leads to the synthesis of cyclometalled PCP iron carbonyl pincer complexes which are active catalytic precursors for the selective dehydrogenative borylation of styrene.

Download Full-text