Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene

2016 ◽  
Vol 45 (27) ◽  
pp. 11101-11108 ◽  
Author(s):  
Shi Jiang ◽  
Samuel Quintero-Duque ◽  
Thierry Roisnel ◽  
Vincent Dorcet ◽  
Mary Grellier ◽  
...  
Keyword(s):  
Efficient Method ◽  
Direct Synthesis ◽  
Iron Carbonyl ◽  
Pincer Complexes ◽  
Hydride Complexes ◽  
Iron Hydride

An efficient method based on the simple metalating reagent Fe(CO)5 leads to the synthesis of cyclometalled PCP iron carbonyl pincer complexes which are active catalytic precursors for the selective dehydrogenative borylation of styrene.

scholarly journals Direct synthesis of doubly deprotonated, dearomatised lutidine PNP Cr and Zr pincer complexes based on isolated K and Li ligand transfer reagents

2016 ◽  
Vol 45 (7) ◽  
pp. 2800-2804 ◽  
Author(s):  
Thomas Simler ◽  
Gilles Frison ◽  
Pierre Braunstein ◽  
Andreas A. Danopoulos
Keyword(s):  
Direct Synthesis ◽  
Pincer Complexes ◽  
Zirconium Complexes ◽  
Ligand Transfer

Double deprotonation of a hybrid bis(phosphino)picoline ligand yields lithium or potassium pincer salts with dearomatised lutidine backbones that afford unusual chromium and zirconium complexes by transmetallation.

New chiral zwitterionic iron hydride complexes with ‘ephosium’ and ‘valphosium’ ligands

1998 ◽  
Vol 566 (1-2) ◽  
pp. 117-123 ◽  
Author(s):  
Jean-Jacques Brunet ◽  
Remi Chauvin ◽  
Jérôme Chiffre ◽  
Sandrine Huguet ◽  
Pascale Leglaye
Keyword(s):  
Hydride Complexes ◽  
Iron Hydride

A novel and efficient method for the direct synthesis of pyrrolyl or indolyl substituted 9,10-dihydrophenanthren-9-ol analogues

2020 ◽  
Vol 61 (7) ◽  
pp. 151500
Author(s):  
Qi Xia ◽  
Xinlei Zhao ◽  
Juan Zhang ◽  
Jiayi Wang ◽  
Gonghua Song
Keyword(s):  
Efficient Method ◽  
Direct Synthesis

Single step, high yield synthesis of para-hydroxy functionalized POCOP ligands and their Ni(ii) pincer derivatives

2015 ◽  
Vol 39 (5) ◽  
pp. 3361-3365 ◽  
Author(s):  
Marco A. García-Eleno ◽  
Esteban Padilla-Mata ◽  
Fabiola Estudiante-Negrete ◽  
Francisco Pichal-Cerda ◽  
Simón Hernández-Ortega ◽  
...  
Keyword(s):  
Efficient Method ◽  
Single Step ◽  
High Yield ◽  
Pincer Complexes

A facile and efficient method is provided for the production of phosphinito ligands [C6H3-5-OH-1,3-(OPR2)2] and their pincer complexes [NiCl{C6H2-4-OH-2,6-(OPR2)2}].

Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals

2017 ◽  
Vol 36 (22) ◽  
pp. 4341-4343 ◽  
Author(s):  
Renyuan Pony Yu ◽  
Jonathan M. Darmon ◽  
Scott P. Semproni ◽  
Zoë R. Turner ◽  
Paul J. Chirik
Keyword(s):  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Hydride Complexes ◽  
Hydrogen Isotope Exchange ◽  
Iron Hydride

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes

2016 ◽  
Vol 55 (46) ◽  
pp. 14373-14377 ◽  
Author(s):  
Prosenjit Daw ◽  
Subrata Chakraborty ◽  
Jai Anand Garg ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Direct Synthesis ◽  
Pincer Complexes ◽  
Dehydrogenative Coupling

Direct synthesis of alkenyl iodides via indium-catalyzed iodoalkylation of alkynes with alcohols and aqueous HI

2018 ◽  
Vol 16 (17) ◽  
pp. 3177-3180 ◽  
Author(s):  
Chao Wu ◽  
Zheng Wang ◽  
Zhan Hu ◽  
Fei Zeng ◽  
Xing-Yu Zhang ◽  
...  
Keyword(s):  
Efficient Method ◽  
Direct Synthesis ◽  
Mild Conditions

A simple and efficient method has been developed for the synthesis of alkenyl iodides through indium-catalyzed iodoalkylation of alkynes with alcohols and aqueous HI under mild conditions.

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