Ferromagnetic coupling in a chloride-bridged erbium single-molecule magnet

2017 ◽  
Vol 53 (53) ◽  
pp. 7322-7324 ◽  
Author(s):  
J. D. Hilgar ◽  
B. S. Flores ◽  
J. D. Rinehart
Keyword(s):  
Single Molecule ◽  
Ferromagnetic Coupling ◽  
Single Molecule Magnet ◽  
High Anisotropy

We present the first ferromagnetically-coupled Er3+ complex with linked, high-anisotropy Er–COT (COT2− = cyclooctatetraene dianion) subunits.

A Linear Metal-Metal Bonded Tri-Iron Single-Molecule Magnet

2021 ◽  
Author(s):  
Anandi Srinivasan ◽  
Rebecca A Musgrave ◽  
Mathieu Rouzieres ◽  
Rodolphe Clerac ◽  
John E. McGrady ◽  
...  
Keyword(s):  
Single Molecule ◽  
Complex Cation ◽  
Trinuclear Complex ◽  
Ferromagnetic Coupling ◽  
Single Molecule Magnet ◽  
Metal Metal

The linear trinuclear complex cation [Fe3(DpyF)4]2+ was prepared as [Fe3(DpyF)4](BF4)2·2CH3CN. With large Fe–Fe distances of 2.78 Å, this complex demonstrates intramolecular ferromagnetic coupling between the anisotropic FeII centers (J/kB =...

scholarly journals A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

2016 ◽  
Vol 128 (37) ◽  
pp. 11248-11251 ◽  
Author(s):  
Thomas Pugh ◽  
Nicholas F. Chilton ◽  
Richard A. Layfield
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy ◽  
Low Symmetry

Linking high anisotropy Dy3 triangles to create a Dy6 single-molecule magnet

2009 ◽  
pp. 1100 ◽  
Author(s):  
Bashir Hussain ◽  
Didier Savard ◽  
Tara J. Burchell ◽  
Wolfgang Wernsdorfer ◽  
Muralee Murugesu
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy

A High Anisotropy Barrier in a Sulfur-Bridged Organodysprosium Single-Molecule Magnet

2012 ◽  
Vol 51 (28) ◽  
pp. 6976-6980 ◽  
Author(s):  
Floriana Tuna ◽  
Charlene A. Smith ◽  
Michael Bodensteiner ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy

scholarly journals A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

2016 ◽  
Vol 55 (37) ◽  
pp. 11082-11085 ◽  
Author(s):  
Thomas Pugh ◽  
Nicholas F. Chilton ◽  
Richard A. Layfield
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy ◽  
Low Symmetry

A High Anisotropy Barrier in a Sulfur-Bridged Organodysprosium Single-Molecule Magnet

2012 ◽  
Vol 124 (28) ◽  
pp. 7082-7086 ◽  
Author(s):  
Floriana Tuna ◽  
Charlene A. Smith ◽  
Michael Bodensteiner ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
...  
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnet ◽  
High Anisotropy

A series of goblet-like heterometallic pentanuclear [LnIIICuII4] clusters featuring ferromagnetic coupling and single-molecule magnet behavior

2012 ◽  
Vol 48 (87) ◽  
pp. 10736 ◽  
Author(s):  
Qilong Zhu ◽  
Shengchang Xiang ◽  
Tianlu Sheng ◽  
Daqiang Yuan ◽  
Chaojun Shen ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ferromagnetic Coupling ◽  
Single Molecule Magnet

scholarly journals A Flexible Approach for Engineering Macrocyclic High Performance Pentagonal Bipyramidal Dy(III) Single-Ion Magnets

2020 ◽  
Author(s):  
Angelos Canaj ◽  
Sourav Dey ◽  
Claire Wilson ◽  
Oscar Céspedes ◽  
Rajaraman Gopalan ◽  
...  
Keyword(s):  
Ab Initio ◽  
Single Molecule ◽  
High Performance ◽  
Macrocyclic Ligand ◽  
Hysteresis Loops ◽  
Ligand Field ◽  
Single Molecule Magnet ◽  
Flexible Approach ◽  
High Anisotropy

A strong uniaxial ligand field generated by the Ph3SiO<sup>-</sup> ligand combined with the weak equatorial field of the macrocyclic ligand LN5, generates [DyIII(LN5)(Ph3SiO)2]+, a pentagonal bipyramidal Dy(III) Single-Molecule Magnet with a high anisotropy barrier of 1108 K, and hysteresis loops open up to 14 K. Based on our synthetic blueprint, we use <i>ab initio</i> calculations to predict changes to the macrocycle to increase the barrier to ~ 1800 K.

A triangular dysprosium with asymmetric central caps featuring ferromagnetic coupling and single-molecule magnet behaviour

2013 ◽  
Vol 42 (29) ◽  
pp. 10413 ◽  
Author(s):  
Si Shen ◽  
Shufang Xue ◽  
Shuang-Yan Lin ◽  
Lang Zhao ◽  
Jinkui Tang
Keyword(s):  
Single Molecule ◽  
Ferromagnetic Coupling ◽  
Single Molecule Magnet
Sign in / Sign up

Export Citation Format

Share Document