Magnesium amide catalyzed selective hydroboration of esters

2017 ◽  
Vol 46 (13) ◽  
pp. 4152-4156 ◽  
Author(s):  
Milan Kr. Barman ◽  
Ashim Baishya ◽  
Sharanappa Nembenna

Cheaper, inexpensive alkaline-earth metal amides as efficient pre-catalysts for the selective hydroboration of a large number of esters.

ChemPhysChem ◽  
2019 ◽  
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Ye‐Qin Guan ◽  
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Xiang-Yu Zhang ◽  
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Bing-Tao Guan

Breaking saline KH: The combined KH/alkaline-earth metal amide catalysts display much better catalytic activity than their components in the hydrogenation of alkenes, suggesting the degradation and activation of saline KH with the metal amides.


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pp. 2822-2828 ◽  
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