Structural diversity and photo-physical and magnetic properties of dimeric to 1D polymeric coordination polymers of lighter lanthanide(iii) dinitrobenzoates

Single-molecule magnets involving monometallic 4f complexes have been investigated extensively in last two decades to understand the factors that govern the slow magnetization relaxation behavior in these complexes and to establish a magneto-structural correlation. The prime goal in this direction is to suppress the temperature independent quantum tunneling of magnetization (QTM) effect via fine-tuning the coordination geometry/microenvironment. Among the various coordination geometries that have been pursued, complexes containing high coordination number around Ln(III) are sparse. Herein, we present a summary of the various synthetic strategies that were used for the assembly of 10- and 12-coordinated Ln(III) complexes. The magnetic properties of such complexes are also described.

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Synthesis, structures, and magnetic properties of one-dimensional Fe–M (M=NiII, CuII) coordination polymers bridged by nitroprusside

Inorganica Chimica Acta ◽

10.1016/j.ica.2006.12.023 ◽

2007 ◽

Vol 360 (8) ◽

pp. 2523-2531 ◽

Cited By ~ 5

Author(s):

Young Sin You ◽

Jung Hee Yoon ◽

Jeong Hak Lim ◽

Hyoung Chan Kim ◽

Chang Seop Hong

Keyword(s):

Magnetic Properties ◽

Coordination Polymers ◽

One Dimensional

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Recent advances in lanthanide coordination polymers and clusters with magnetocaloric effect or single-molecule magnet behavior

Dalton Transactions ◽

10.1039/d1dt02797b ◽

2021 ◽

Author(s):

Jun-Jie Hu ◽

Yan Peng ◽

Sui-Jun Liu ◽

He-Rui Wen

Keyword(s):

Quantum Computing ◽

Low Temperature ◽

Magnetocaloric Effect ◽

Coordination Polymers ◽

Single Molecule ◽

Information Storage ◽

Lanthanide Ions ◽

Single Molecule Magnets ◽

Single Molecule Magnet ◽

Lanthanide Coordination Polymers

The molecular magnetorefrigerant materials for low-temperature magnetic refrigeration and single-molecule magnets for high-density information storage and quantum computing have received extensive attention from chemists and magnetic experts. Lanthanide ions with...

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Synthesis, structural characterization and magnetic properties of one-dimensional Cu(II)-azido coordination polymers

Polyhedron ◽

10.1016/j.poly.2017.09.035 ◽

2017 ◽

Vol 138 ◽

pp. 177-184 ◽

Cited By ~ 9

Author(s):

Febee R. Louka ◽

Salah S. Massoud ◽

Tamim K. Haq ◽

Masayuki Koikawa ◽

Masahiro Mikuriya ◽

...

Keyword(s):

Magnetic Properties ◽

Coordination Polymers ◽

Structural Characterization ◽

One Dimensional

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Application of the Landau-Luttinger Liquid Formulation to the Study of the Magnetic Properties of the 1-D Hubbard Model

International Journal of Modern Physics B ◽

10.1142/s021797929100002x ◽

1991 ◽

Vol 05 (01n02) ◽

pp. 3-30 ◽

Cited By ~ 3

Author(s):

J. Carmelo ◽

P. Horsch ◽

P.A. Bares ◽

A.A. Ovchinnikov

Keyword(s):

Magnetic Field ◽

Magnetic Properties ◽

Low Temperature ◽

Hubbard Model ◽

Luttinger Liquid ◽

Liquid Formulation ◽

One Dimensional ◽

Spin Excitations ◽

Arbitrary Strength ◽

The One

The Landau-Luttinger liquid formulation is used to investigate the physics of the one-dimensional Hubbard model in a magnetic field of arbitrary strength H. The low lying charge and spin excitations are studied. A novel branch of sound wave-like spin excitations arises for H>0. The low temperature thermodynamics is considered in some detail.

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Designing Multifunctional 5-Cyanoisophthalate-Based Coordination Polymers as Single-Molecule Magnets, Adsorbents, and Luminescent Materials

Inorganic Chemistry ◽

10.1021/acs.inorgchem.6b01845 ◽

2016 ◽

Vol 55 (21) ◽

pp. 11230-11248 ◽

Cited By ~ 28

Author(s):

Jose M. Seco ◽

Itziar Oyarzabal ◽

Sonia Pérez-Yáñez ◽

Javier Cepeda ◽

Antonio Rodríguez-Diéguez

Keyword(s):

Coordination Polymers ◽

Single Molecule ◽

Luminescent Materials ◽

Single Molecule Magnets

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Effects of Pressure on Two-Dimensional Networked Single-Molecule Magnets Exhibiting AC-Field-Switchable Magnetic Properties

Journal of the Physical Society of Japan ◽

10.1143/jpsj.81.064716 ◽

2012 ◽

Vol 81 (6) ◽

pp. 064716 ◽

Cited By ~ 3

Author(s):

Masaki Mito ◽

Masashi Ogawa ◽

Hiroyuki Deguchi ◽

Masahiro Yamashita ◽

Hitoshi Miyasaka

Keyword(s):

Magnetic Properties ◽

Single Molecule ◽

Two Dimensional ◽

Single Molecule Magnets ◽

Ac Field

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Multireference Ab Initio Studies of Magnetic Properties of Terbium-Based Single-Molecule Magnets

The Journal of Physical Chemistry A ◽

10.1021/acs.jpca.9b03708 ◽

2019 ◽

Vol 123 (32) ◽

pp. 6996-7006 ◽

Cited By ~ 6

Author(s):

Ryan Pederson ◽

Aleksander L. Wysocki ◽

Nicholas Mayhall ◽

Kyungwha Park

Keyword(s):

Magnetic Properties ◽

Ab Initio ◽

Single Molecule ◽

Single Molecule Magnets

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Structural diversity, gas adsorption and magnetic properties of three coordination polymers based on a rigid multicarboxylate ligand

CrystEngComm ◽

10.1039/d0ce01201g ◽

2020 ◽

Vol 22 (42) ◽

pp. 7046-7053

Author(s):

Lingling Gao ◽

Yongjun Bian ◽

Yuan Tian ◽

Yongqiang Chen ◽

Tuoping Hu

Keyword(s):

Magnetic Properties ◽

Benzoic Acid ◽

Coordination Polymers ◽

Gas Adsorption ◽

Structural Diversity ◽

Acid Ligand

A pictogram: the gas adsorption and magnetic properties of three Co(ii) coordination polymers constructed from 3,5-di(2′,5′-dicarboxylphenyl)benzoic acid ligand have been explored.

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