Bis(oxazoline)-derived N-heterocyclic carbene ligated rare-earth metal complexes: synthesis, structure, and polymerization performance

2018 ◽  
Vol 47 (39) ◽  
pp. 13815-13823 ◽  
Author(s):  
Yu Pan ◽  
Aijing Zhao ◽  
Yang Li ◽  
Wenqiang Li ◽  
Yat-Ming So ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Rare Earth Complexes ◽  
Good Activity ◽  
First Time ◽  
Rare Earth Metal Complexes

Bis(oxazoline)-derived NHC supported rare-earth complexes have been synthesized for the first time and showed good activity for 1-hexene (co)polymerization.

Synthesis and structural characterization of amido heteroscorpionate rare-earth metal complexes and hydroamination of aminoalkenes

2015 ◽  
Vol 39 (10) ◽  
pp. 7672-7681 ◽  
Author(s):  
Antonio Otero ◽  
Agustín Lara-Sánchez ◽  
José A. Castro-Osma ◽  
Isabel Márquez-Segovia ◽  
Carlos Alonso-Moreno ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Structural Characterization ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Rare Earth Complexes ◽  
Rare Earth Metal Complexes

New amide heteroscorpionate rare-earth complexes were developed and used as efficient catalysts for the intramolecular hydroamination of aminoalkenes.

Small molecule activation by mixed methyl/methylidene rare earth metal complexes

2016 ◽  
Vol 45 (15) ◽  
pp. 6641-6649 ◽  
Author(s):  
Jianquan Hong ◽  
Zhenhua Li ◽  
Zhening Chen ◽  
Linhong Weng ◽  
Xigeng Zhou ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Small Molecule ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Rare Earth Complexes ◽  
Small Molecule Activation ◽  
Rare Earth Metal Complexes

Diverse reactivity patterns of mixed tetramethyl/methylidene rare-earth complexes bearing bulky benzamidinate coligands with PhCN, alkynes, and CS2 have been established and fully characterized.

Sign in / Sign up

Export Citation Format

Share Document