Integration of metal-free ring-opening metathesis polymerization and organocatalyzed ring-opening polymerization through a bifunctional initiator

2019 ◽  
Vol 10 (23) ◽  
pp. 2975-2979 ◽  
Author(s):  
Pengtao Lu ◽  
Andrew J. Boydston
Keyword(s):  
Block Copolymers ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free

We demonstrate the first integration of metal-free ROMP and organocatalyzed ROP to provide entirely metal-free syntheses of block copolymers.

scholarly journals Metal-Free Ring-Opening Metathesis Polymerization

2015 ◽  
Vol 137 (4) ◽  
pp. 1400-1403 ◽  
Author(s):  
Kelli A. Ogawa ◽  
Adam E. Goetz ◽  
Andrew J. Boydston
Keyword(s):  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free

Comparison of Pyrylium and Thiopyrylium Photooxidants in Metal-Free Ring-Opening Metathesis Polymerization

Synlett ◽  
2016 ◽  
Vol 27 (05) ◽  
pp. 759-762 ◽  
Author(s):  
Andrew Boydston ◽  
Laura Pascual ◽  
Damian Dunford ◽  
Adam Goetz ◽  
Kelli Ogawa
Keyword(s):  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free

An Ion‐Pairing Approach to Stereoselective Metal‐Free Ring‐Opening Metathesis Polymerization

2021 ◽  
Author(s):  
Xuejin Yang ◽  
Sean R. Gitter ◽  
Allison G. Roessler ◽  
Paul M. Zimmerman ◽  
Andrew Jackson Boydston
Keyword(s):  
Ring Opening ◽  
Ion Pairing ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free

A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene

2021 ◽  
Author(s):  
Xuejin Yang ◽  
Laura M. Murphy ◽  
Farihah M. Haque ◽  
Scott M. Grayson ◽  
Andrew J. Boydston
Keyword(s):  
Ring Opening ◽  
Efficient Synthesis ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free ◽  
Highly Efficient

We have developed a highly efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP) and investigated the Tg–Mn dependence of linear pDCPD.

scholarly journals Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions

2019 ◽  
Vol 141 (42) ◽  
pp. 16605-16609 ◽  
Author(s):  
Tim Krappitz ◽  
Kristina Jovic ◽  
Florian Feist ◽  
Hendrik Frisch ◽  
Vincent P. Rigoglioso ◽  
...  
Keyword(s):  
Ring Opening ◽  
Vinyl Monomers ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free ◽  
Polymerization Conditions

scholarly journals Investigation of Tacticity and Living Characteristics of Photoredox-Mediated Metal-Free Ring-Opening Metathesis Polymerization

2017 ◽  
Vol 38 (13) ◽  
pp. 1600766 ◽  
Author(s):  
Laura M. M. Pascual ◽  
Adam E. Goetz ◽  
Adrienne M. Roehrich ◽  
Andrew J. Boydston
Keyword(s):  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free

An Ion‐Pairing Approach to Stereoselective Metal‐Free Ring‐Opening Metathesis Polymerization

2021 ◽  
Author(s):  
Xuejin Yang ◽  
Sean R. Gitter ◽  
Allison G. Roessler ◽  
Paul M. Zimmerman ◽  
Andrew Jackson Boydston
Keyword(s):  
Ring Opening ◽  
Ion Pairing ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free

Expanded Functionality of Polymers Prepared Using Metal-Free Ring-Opening Metathesis Polymerization

2016 ◽  
Vol 5 (5) ◽  
pp. 579-582 ◽  
Author(s):  
Adam E. Goetz ◽  
Laura M. M. Pascual ◽  
Damian G. Dunford ◽  
Kelli A. Ogawa ◽  
Daniel B. Knorr ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Free Ring ◽  
Metathesis Polymerization ◽  
Metal Free
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