Facile access to functionalized chiral secondary benzylic boronic esters via catalytic asymmetric hydroboration

Boronic Esters ◽

Allylic and homoallylic phosphonates undergo asymmetric hydroboration yielding chiral boronic esters (yields up to 86%, enantiomer ratios up to 99 : 1).

Synthesis of Chiral Tertiary Boronic Esters by Oxime-Directed Catalytic Asymmetric Hydroboration

Angewandte Chemie International Edition ◽

10.1002/anie.201509137 ◽

2015 ◽

Vol 55 (4) ◽

pp. 1465-1469 ◽

Cited By ~ 63

Author(s):

Veronika M. Shoba ◽

Nathan C. Thacker ◽

Andrew J. Bochat ◽

James M. Takacs

Keyword(s):

Boronic Esters ◽

Synthesis of Chiral Tertiary Boronic Esters by Oxime-Directed Catalytic Asymmetric Hydroboration

Angewandte Chemie ◽

10.1002/ange.201509137 ◽

2015 ◽

Vol 128 (4) ◽

pp. 1487-1491 ◽

Cited By ~ 24

Author(s):

Veronika M. Shoba ◽

Nathan C. Thacker ◽

Andrew J. Bochat ◽

James M. Takacs

Keyword(s):

Boronic Esters ◽

Synthesis of Chiral Tertiary Boronic Esters: Phosphonate-Directed Catalytic Asymmetric Hydroboration of Trisubstituted Alkenes

Journal of the American Chemical Society ◽

10.1021/jacs.7b02324 ◽

2017 ◽

Vol 139 (17) ◽

pp. 6066-6069 ◽

Cited By ~ 38

Author(s):

Suman Chakrabarty ◽

James M. Takacs

Keyword(s):

Boronic Esters ◽

Catalytic Asymmetric ◽

Trisubstituted Alkenes

ChemInform Abstract: Synthesis of Chiral Tertiary Boronic Esters by Oxime-Directed Catalytic Asymmetric Hydroboration.

ChemInform ◽

10.1002/chin.201622026 ◽

2016 ◽

Vol 47 (22) ◽

Author(s):

Veronika M. Shoba ◽

Nathan C. Thacker ◽

Andrew J. Bochat ◽

James M. Takacs

Keyword(s):

Boronic Esters ◽

Phosphonate-Directed Catalytic Asymmetric Hydroboration: Delivery of Boron to the More Substituted Carbon, Leading to Chiral Tertiary Benzylic Boronic Esters

ACS Catalysis ◽

10.1021/acscatal.8b03591 ◽

2018 ◽

Vol 8 (11) ◽

pp. 10530-10536 ◽

Cited By ~ 8

Author(s):

Suman Chakrabarty ◽

James M. Takacs

Keyword(s):

Boronic Esters ◽

Amide-Directed Catalytic Asymmetric Hydroboration of Trisubstituted Alkenes

Journal of the American Chemical Society ◽

10.1021/ja908257x ◽

2010 ◽

Vol 132 (6) ◽

pp. 1740-1741 ◽

Cited By ~ 86

Author(s):

Sean M. Smith ◽

James M. Takacs

Keyword(s):

Catalytic Asymmetric ◽

Trisubstituted Alkenes

ChemInform Abstract: Catalytic Asymmetric Carbon-Carbon Bond Forming Reactions: Preparation of Optically Enriched 2-Aryl Propionic Acids by a Catalytic Asymmetric Hydroboration-Homologation Sequence.

ChemInform ◽

10.1002/chin.199928120 ◽

2010 ◽

Vol 30 (28) ◽

pp. no-no

Author(s):

Austin C. Chen ◽

Li Ren ◽

Cathleen M. Crudden

Keyword(s):

Carbon Bond ◽

Bond Forming ◽

Carbon Carbon Bond ◽

Bond Forming Reactions ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

Catalytic asymmetric hydroboration of heterofunctional allylic substrates: an efficient heterogenized version

Tetrahedron Asymmetry ◽

10.1016/j.tetasy.2007.03.031 ◽

2007 ◽

Vol 18 (8) ◽

pp. 911-914 ◽

Cited By ~ 9

Author(s):

Vanesa Lillo ◽

Elena Fernández ◽

Anna M. Segarra

Keyword(s):

ChemInform Abstract: Catalytic Asymmetric Hydroboration with Oxazaborolidines.

ChemInform ◽

10.1002/chin.199116074 ◽

2010 ◽

Vol 22 (16) ◽

pp. no-no

Author(s):

J. M. BROWN ◽

G. C. LLOYD-JONES

Keyword(s):

Two-stage optimization of a supramolecular catalyst for catalytic asymmetric hydroboration

Chemical Communications ◽

10.1039/c1cc16146f ◽

2012 ◽

Vol 48 (2) ◽

pp. 263-265 ◽

Cited By ~ 26

Author(s):

Shin A. Moteki ◽

Kazuya Toyama ◽

Zeyu Liu ◽

Jing Ma ◽

Andrea E. Holmes ◽

...

Keyword(s):

Two Stage ◽