An untethered C3v-symmetric triarylphosphine oxide locked by intermolecular hydrogen bonding

2019 ◽  
Vol 55 (26) ◽  
pp. 3761-3764 ◽  
Author(s):  
Timothy G. Carroll ◽  
Camden Hunt ◽  
Rachel Garwick ◽  
Guang Wu ◽  
Roman Dobrovetsky ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Intermolecular Hydrogen Bonding ◽  
State Structure ◽  
Solid State Structure

A C3v-symmetric triarylphosphine oxide locked into conformation by H-bonding and displaying an extended MOF-like solid-state structure is reported.

Intermolecular hydrogen-bonding in the solid-state structure of CpFe(CN)2(PTAH)

2003 ◽  
Vol 666 (1-2) ◽  
pp. 49-53 ◽  
Author(s):  
Donald J Darensbourg ◽  
Andrea L Phelps ◽  
M.Jason Adams ◽  
Jason C Yarbrough
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Intermolecular Hydrogen Bonding ◽  
State Structure ◽  
Solid State Structure

Moschamindole

2000 ◽  
Vol 57 (1) ◽  
pp. o81-o82 ◽  
Author(s):  
Philip J. Cox ◽  
Margot Fergusson ◽  
Lutfun Nahar ◽  
Satyajit D. Sarker
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Intermolecular Hydrogen Bonding ◽  
State Structure ◽  
Solid State Structure ◽  
Solution State

The solid state structure of moschamindole {systematic name: 10-[2-(4-hydroxy-3-methoxyphenyl)]-1,2,3,4,10,10a-hexahydro-6H-furo[2,3,4-jk]pyrrolo[4,3,2-ef]-3-benzazocin-1-one}, C20H18N2O4is similar to its solution state structure, previously determined by NMR, and evidence of intermolecular hydrogen bonding is now presented.

scholarly journals Crystal structure of 2-cyano-1-methylpyridinium tetrafluoroborate

2015 ◽  
Vol 71 (10) ◽  
pp. o697-o698 ◽  
Author(s):  
Francesca A. Vaccaro ◽  
Lynn V. Koplitz ◽  
Joel T. Mague
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Solid State ◽  
Three Dimensional ◽  
Asymmetric Unit ◽  
State Structure ◽  
Solid State Structure ◽  
Two Component

The asymmetric unit of the title salt, C7H7N2+·BF4−, comprises two independent but nearly identical formula units. The solid-state structure comprises corrugated layers of cations and anions, formed by C—H...F hydrogen bonding, that are approximately parallel to (010). Further C—H...F hydrogen bonding consolidates the three-dimensional architecture. The sample was refined as a two-component non-merohedral twin.

scholarly journals Solid-state structure and electronic states of hydrogen-bonded dimer of pyridyl-substituted tetrathiafulvalene salted with PF6−

RSC Advances ◽  
2017 ◽  
Vol 7 (11) ◽  
pp. 6236-6241 ◽  
Author(s):  
Tomoaki Kanetou ◽  
Ryo Tsunashima ◽  
Norihisa Hoshino ◽  
Tomoyuki Akutagawa
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Dipole Moment ◽  
Solid State ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Electronic States ◽  
Electronic Systems ◽  
State Structure ◽  
Solid State Structure

Our results clarified uniqueness in hydrogen bonding TTFPy dimer in which proton in hydrogen bond was thermally fluctuated. In addition, the fluctuation was coupled with π-electronic systems of TTF moiety where electric dipole moment was amplified.

trans-Dichlorobis[diphenyl(p-tolyl)phosphine]palladium(II)

2006 ◽  
Vol 62 (7) ◽  
pp. m1705-m1707 ◽  
Author(s):  
Gideon Steyl ◽  
Leo Kirsten ◽  
Andreas Roodt
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Planar Geometry ◽  
Dimensional Chain ◽  
Intermolecular Hydrogen Bonding ◽  
State Structure ◽  
Metal Centre ◽  
One Dimensional ◽  
Hydrogen Bonding Pattern ◽  
Square Planar

The centrosymmetric title compound, [PdCl2(C19H17P)2], crystallizes with a square-planar geometry about the PdII metal centre. The most important bond distances include Pd—P (trans P) of 2.3404 (9) Å and Pd—Cl (trans Cl) of 2.2977 (12) Å. Weak intra- and intermolecular hydrogen bonding is observed in the solid-state structure between the chloro and phenyl H atoms. This weak intermolecular hydrogen-bonding pattern forms a one-dimensional chain along the b axis.

scholarly journals Hydrogen-bonding motifs in the solid-state structure of ferroceneboronic acid

2004 ◽  
Vol 60 (4) ◽  
pp. m441-m443 ◽  
Author(s):  
Christopher Bresner ◽  
Simon Aldridge ◽  
Ian A. Fallis ◽  
Li-Ling Ooi
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
State Structure ◽  
Solid State Structure

Supramolecular Structures by Hydrogen Bonding: The Solid-State Structure of Tris[3-(3-dimethylamino-1-oxoprop-2-enyl)phenyl]phosphane Oxide

2007 ◽  
Vol 2007 (5) ◽  
pp. 777-781
Author(s):  
Andreas Reis ◽  
Yu Sun ◽  
Gotthelf Wolmershäuser ◽  
Werner R. Thiel
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Supramolecular Structures ◽  
State Structure ◽  
Solid State Structure

scholarly journals Crystal structure of 2-cyano-1-methylpyridinium perchlorate

2015 ◽  
Vol 71 (11) ◽  
pp. o852-o853
Author(s):  
Vu D. Nguyen ◽  
Cameron A. McCormick ◽  
Joel T. Mague ◽  
Lynn V. Koplitz
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Solid State ◽  
Three Dimensional ◽  
Asymmetric Unit ◽  
State Structure ◽  
Solid State Structure ◽  
Pyridinium Perchlorate

The asymmetric unit of the title salt, C7H7N2+·ClO4−, comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supramolecular layers are stabilized and connected by C—H...O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridinium–perchlorate N...O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

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