scholarly journals Mechanistic insights of anionic ligand exchange and fullerene reduction with magnesium(i) compounds

2019 ◽  
Vol 48 (45) ◽  
pp. 16936-16942 ◽  
Author(s):  
Samuel R. Lawrence ◽  
David B. Cordes ◽  
Alexandra M. Z. Slawin ◽  
Andreas Stasch
Keyword(s):  
Ligand Exchange ◽  
Associative Mechanism ◽  
Anionic Ligand ◽  
Anionic Ligands

Exchange of anionic ligands on the Mg22+ ion via an associative mechanism can be facile and depends on ligand sterics and shape.

scholarly journals Amino acids as chiral anionic ligands for ruthenium based asymmetric olefin metathesis

2015 ◽  
Vol 51 (18) ◽  
pp. 3870-3873 ◽  
Author(s):  
Elisa Ivry ◽  
Amos Ben-Asuly ◽  
Israel Goldberg ◽  
N. Gabriel Lemcoff
Keyword(s):  
Amino Acids ◽  
Ligand Exchange ◽  
Olefin Metathesis ◽  
Anionic Ligand ◽  
Anionic Ligands ◽  
Metathesis Reactions

Anionic ligand exchange by amino acids readily produce chiral ruthenium benzylidenes that catalyze asymmetric olefin metathesis reactions.

scholarly journals Simultaneous Cationic and Anionic Ligand Exchange For Colloidally Stable CsPbBr3 Nanocrystals

2019 ◽  
Vol 4 (4) ◽  
pp. 819-824 ◽  
Author(s):  
Muhammad Imran ◽  
Palvasha Ijaz ◽  
Luca Goldoni ◽  
Daniela Maggioni ◽  
Urko Petralanda ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Anionic Ligand

Anionic Ligand Exchange in Hoveyda−Grubbs Ruthenium(II) Benzylidenes

2006 ◽  
Vol 25 (24) ◽  
pp. 5696-5698 ◽  
Author(s):  
Kiyotaka Tanaka ◽  
Volker P. W. Böhm ◽  
David Chadwick ◽  
Michael Roeper ◽  
D. Christopher Braddock
Keyword(s):  
Ligand Exchange ◽  
Anionic Ligand

Seleniranium Ions Undergo π-Ligand Exchange via an Associative Mechanism in the Gas Phase

2017 ◽  
Vol 82 (12) ◽  
pp. 6289-6297 ◽  
Author(s):  
S. Fern Lim ◽  
Benjamin L. Harris ◽  
George N. Khairallah ◽  
E.J. Bieske ◽  
Philippe Maître ◽  
...  
Keyword(s):  
Gas Phase ◽  
Ligand Exchange ◽  
Associative Mechanism

Anionic Ligand Exchange on ZrPO4Cl(dmso):  Alkoxide and Carboxylate Derivatives

2004 ◽  
Vol 43 (1) ◽  
pp. 368-374 ◽  
Author(s):  
Riccardo Vivani ◽  
Silvia Masci ◽  
Giulio Alberti
Keyword(s):  
Ligand Exchange ◽  
Anionic Ligand

Vacuum-driven anionic ligand exchange in Buchmeiser–Hoveyda–Grubbs ruthenium(II) benzylidenes

2007 ◽  
Vol 48 (30) ◽  
pp. 5301-5303 ◽  
Author(s):  
D. Christopher Braddock ◽  
Kiyotaka Tanaka ◽  
David Chadwick ◽  
Volker P.W. Böhm ◽  
Michael Roeper
Keyword(s):  
Ligand Exchange ◽  
Anionic Ligand

Influence of Anionic Ligand Exchange in Latent Sulfur-Chelated Ruthenium Precatalysts

2018 ◽  
Vol 57 (24) ◽  
pp. 15592-15599 ◽  
Author(s):  
Elisa Ivry ◽  
Noy B. Nechmad ◽  
Mark Baranov ◽  
Israel Goldberg ◽  
N. Gabriel Lemcoff
Keyword(s):  
Ligand Exchange ◽  
Anionic Ligand

scholarly journals Poly[bis(ethanol)(μ4-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato)cadmium]

2013 ◽  
Vol 69 (11) ◽  
pp. m577-m578
Author(s):  
Nakeun Ko ◽  
Jaheon Kim
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Two Dimensional ◽  
Ethanol Molecule ◽  
Anionic Ligand ◽  
Distorted Octahedral ◽  
Anionic Ligands ◽  
Polymeric Layer

In the title compound, [Cd(C8F4O4)(C2H5OH)2]n, the CdIIcation sits on an inversion centre and is coordinated by six O atoms from four tetrafluorobenzene-1,4-dicarboxylate anions and two ethanol molecules in a distorted octahedral geometry. The anionic ligand is also located on an inversion centre, and connects four CdIIcations, generating a two-dimensional polymeric layer parallel to theabplane. Within the layer, the ethanol molecule links F and O atoms of the nearest anionic ligandsviaO—H...O and O—H...F hydrogen bonds. The ethyl group of the ethanol molecule is disordered over two positions with an occupancy ratio of 0.567 (10):0.433 (10).

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