Enhanced laser-induced breakdown spectroscopy using the combination of circular and annular laser pulses

2019 ◽  
Vol 34 (10) ◽  
pp. 1982-1987 ◽  
Author(s):  
Ran Hai ◽  
Liying Sun ◽  
Ding Wu ◽  
Zhonglin He ◽  
Harse Sattar ◽  
...  

Novel DP-LIBS is an effective way of significantly enhancing the spectral emission intensity and reducing LOD of trace elements.

2019 ◽  
Vol 34 (12) ◽  
pp. 2378-2384 ◽  
Author(s):  
Ran Hai ◽  
Zhonglin He ◽  
Ding Wu ◽  
Weina Tong ◽  
Harse Sattar ◽  
...  

During laser ablation, the spectral emission intensity, plasma temperature and electron density increased significantly with increasing sample temperature.


2020 ◽  
Vol 1 (2) ◽  
pp. 5-8
Author(s):  
Komang Gde Suastika, Heri Suyanto, Gunarjo, Sadiana, Darmaji

Abstract - Laser-Induced Breakdown Spectroscopy (LIBS) is one method of atomic emission spectroscopy using laser ablation as an energy source. This method is used to characterize the type of amethysts that originally come from Sukamara, Central Kalimantan. The result of amethyst characterization can be used as a reference for claiming the natural wealth of the amethyst. The amethyst samples are directly taken from the amethyst mining field in the District Gem Amethyst and consist of four color variations: white, black, yellow, and purple. These samples were analyzed by LIBS, using laser energy of 120 mJ, delay time detection of 2 μs and accumulation of 3, with and without cleaning. The purpose of this study is to determine emission spectra characteristics, contained elements, and physical characteristics of each amethyst sample. The spectra show that the amethyst samples contain some elements such as Al, Ca, K, Fe, Gd, Ba, Si, Be, H, O, N, Cl and Pu with various emission intensities. The value of emission intensity corresponds to concentration of element in the sample. Hence, the characteristics of the amethysts are based on their concentration value. The element with the highest concentration in all samples is Si, which is related to the chemical formula of SiO2. The element with the lowest concentration in all samples is Ca that is found in black and yellow amethysts. The emission intensity of Fe element can distinguish between white, purple, and yellow amethyst. If Fe emission intensity is very low, it indicates yellow sample. Thus, we may conclude that LIBS is a method that can be used to characterize the amethyst samples.Key words: amethyst, impurity, laser-induced, breakdown spectroscopy, characteristic, gemstones


2019 ◽  
Vol 18 (03n04) ◽  
pp. 1940022
Author(s):  
V. V. Kiris ◽  
A. V. Butsen ◽  
E. A. Ershov-Pavlov ◽  
M. I. Nedelko ◽  
A. A. Nevar

Composite Ag–Cu and Ni–C nanoparticles were synthesized by laser ablation and spark discharge in liquid, respectively. An amplification of the signal during laser induced breakdown spectroscopy was observed after deposition of the nanoparticles on the surface of an aluminum foil. The emission intensity of the laser plume increased from 2 to 20 times depending on the spectral lines used for the measurements. The intensity growth was higher for Ag–Cu nanoparticles.


2015 ◽  
Vol 17 (2) ◽  
pp. 147-152 ◽  
Author(s):  
Jie Shen ◽  
Zhengcai Yang ◽  
Xiaoliang Liu ◽  
Yanchao Shi ◽  
Peixi Zhao ◽  
...  

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