Selective synthesis of trisubstituted pyrroles through the reactions of alkynyl Fischer carbene complexes with oxazolones

The unexpected reactivity of fluorinated oxazolones with alkynyl Fischer carbenes is reported. The loss of the –CF3 and a cascade process involving nucleophilic additions were observed.

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The DFT study on pentannulation reaction of tungsten Fischer carbene complexes

Computational and Theoretical Chemistry ◽

10.1016/j.comptc.2020.113121 ◽

2021 ◽

Vol 1196 ◽

pp. 113121

Author(s):

Mirana C. Angel ◽

Victor L. Prutyanov

Keyword(s):

Dft Study ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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ChemInform Abstract: Polycyclic Cyclopropanes from Reactions of Alkene-Containing Fischer Carbene Complexes and Alkynes: A Formal Synthesis of (.+-.)-Carabrone.

ChemInform ◽

10.1002/chin.199547228 ◽

2010 ◽

Vol 26 (47) ◽

pp. no-no

Author(s):

T. R. HOYE ◽

J. R. VYVYAN

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Formal Synthesis ◽

Fischer Carbene

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A New Synthesis of Allyl Sulfoxides via Nucleophilic Addition of Sulfinyl Carbanions to Group 6 Fischer Carbene Complexes.

ChemInform ◽

10.1002/chin.200533097 ◽

2005 ◽

Vol 36 (33) ◽

Author(s):

Jose Barluenga ◽

Martin Fananas-Mastral ◽

Fernando Aznar

Keyword(s):

Nucleophilic Addition ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

New Synthesis ◽

Group 6

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Coupling of Fischer Carbene Complexes with Conjugated Enyne−Aldehydes and Ketones: A Novel Synthesis of Furan Derivatives

The Journal of Organic Chemistry ◽

10.1021/jo9803939 ◽

1998 ◽

Vol 63 (14) ◽

pp. 4564-4565 ◽

Cited By ~ 48

Author(s):

James W. Herndon ◽

Haixia Wang

Keyword(s):

Fischer Carbene Complexes ◽

Furan Derivatives ◽

Carbene Complexes ◽

Fischer Carbene ◽

Novel Synthesis ◽

Aldehydes And Ketones

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ChemInform Abstract: Coupling of Fischer Carbene Complexes with Conjugated Enyne-Aldehydes and Ketones: A Novel Synthesis of Furan Derivatives.

ChemInform ◽

10.1002/chin.199849132 ◽

2010 ◽

Vol 29 (49) ◽

pp. no-no

Author(s):

J. W. HERNDON ◽

H. WANG

Keyword(s):

Fischer Carbene Complexes ◽

Furan Derivatives ◽

Carbene Complexes ◽

Fischer Carbene ◽

Novel Synthesis ◽

Aldehydes And Ketones

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Computational and experimental tools in solving some mechanistic problems in the chemistry of Fischer carbene complexes

Chemical Communications ◽

10.1039/b807806h ◽

2008 ◽

pp. 4671 ◽

Cited By ~ 43

Author(s):

Miguel A. Sierra ◽

Israel Fernández ◽

Fernando P. Cossío

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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Selective Remote Functionalization of Alkyl Side Chains in the Coupling of Fischer Carbene Complexes with Conjugated Enediynes

Tetrahedron ◽

10.1016/s0040-4020(99)01100-x ◽

2000 ◽

Vol 56 (15) ◽

pp. 2175-2182 ◽

Cited By ~ 22

Author(s):

Yi Zhang ◽

James W. Herndon

Keyword(s):

Side Chains ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Alkyl Side Chains

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Formation of Fischer Carbene Complexes in Asymmetric Aldol-Type Condensation of an Isocyanide Component on Bis(oxazolinyl)phenylrhodium(III) Complexes with Aldehydes: Stereochemistry, Structural Characterization, and Mechanistic Studies

Organometallics ◽

10.1021/om011011j ◽

2002 ◽

Vol 21 (8) ◽

pp. 1684-1696 ◽

Cited By ~ 32

Author(s):

Yukihiro Motoyama ◽

Kayoko Shimozono ◽

Katsuyuki Aoki ◽

Hisao Nishiyama

Keyword(s):

Structural Characterization ◽

Mechanistic Studies ◽

Fischer Carbene Complexes ◽

Asymmetric Aldol ◽

Carbene Complexes ◽

Fischer Carbene

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Amine-Catalyzed Coupling of Aldehydes and Ketenes Derived from Fischer Carbene Complexes: Formation of β-Lactones and Enol Ethers

The Journal of Organic Chemistry ◽

10.1021/jo034476n ◽

2003 ◽

Vol 68 (15) ◽

pp. 6056-6059 ◽

Cited By ~ 20

Author(s):

Craig A. Merlic ◽

Brandon C. Doroh

Keyword(s):

Fischer Carbene Complexes ◽

Enol Ethers ◽

Carbene Complexes ◽

Fischer Carbene

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Total Synthesis of Carbazoquinocin C: Application of the o-Benzannulation of Fischer Carbene Complexes to Carbazole-3,4-quinone Alkaloids.

ChemInform ◽

10.1002/chin.200424177 ◽

2004 ◽

Vol 35 (24) ◽

Author(s):

Manish Rawat ◽

William D. Wulff

Keyword(s):

Total Synthesis ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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