Photoelimination of nitrogen from adamantane and pentacycloundecane (PCU) diazirines: a spectroscopic study and supramolecular control
2019 ◽
Vol 18
(7)
◽
pp. 1806-1822
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Nitrogen photoelimination delivers carbenes from diazirines. Protonation of singlet carbenes was detected based on the PCU skeleton rearrangement. Complexation of diazirines changes the relative singlet/triplet ratio of carbene products.
1965 ◽
Vol 5
◽
pp. 120-130
1983 ◽
Vol 44
(C10)
◽
pp. C10-191-C10-194
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