UO22+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex

James T. Brewster; Harrison D. Root; Daniel Mangel; Adam Samia; Hadiqa Zafar; Adam C. Sedgwick; Vincent M. Lynch; Jonathan L. Sessler

doi:10.1039/c9sc01593k

UO22+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex

Chemical Science ◽

10.1039/c9sc01593k ◽

2019 ◽

Vol 10 (21) ◽

pp. 5596-5602 ◽

Cited By ~ 8

Author(s):

James T. Brewster ◽

Harrison D. Root ◽

Daniel Mangel ◽

Adam Samia ◽

Hadiqa Zafar ◽

...

Keyword(s):

Uranyl Complex ◽

Ring Contraction ◽

Acid Catalyzed ◽

Expanded Porphyrin

A new mixed hexaphyrin, pyrihexaphyrin (0.1.0.0.1.0) (1), was prepared via an acid catalyzed cyclization between 5,5′-(pyridine-2,6-diyl)bis(pyrrole-2-carbaldehyde) (2) and terpyrrole (3).

Download Full-text

Correction: UO22+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex

Chemical Science ◽

10.1039/c9sc90138h ◽

2019 ◽

Vol 10 (29) ◽

pp. 7119-7119

Author(s):

James T. Brewster ◽

Harrison D. Root ◽

Daniel Mangel ◽

Adam Samia ◽

Hadiqa Zafar ◽

...

Keyword(s):

Uranyl Complex ◽

Ring Contraction ◽

Expanded Porphyrin

Correction for ‘UO22+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex’ by James T. Brewster et al., Chem. Sci., 2019, 10, 5596–5602.

Download Full-text

ChemInform Abstract: ACID-CATALYZED RING CONTRACTION OF STEROIDAL 1α,2α-EPOXY-4-EN-3-ONES

Chemischer Informationsdienst ◽

10.1002/chin.197710354 ◽

1977 ◽

Vol 8 (10) ◽

pp. no-no

Author(s):

A. M. MAIONE ◽

I. TORRINI ◽

A. ROMEO

Keyword(s):

Ring Contraction ◽

Acid Catalyzed

Download Full-text

ChemInform Abstract: ACID-CATALYZED RING CONTRACTION OF STEROIDAL 4β,5β-EPOXY-1-EN-3-ONES

Chemischer Informationsdienst ◽

10.1002/chin.197923281 ◽

1979 ◽

Vol 10 (23) ◽

Author(s):

A. M. MAIONE ◽

I. TORRINI ◽

A. ROMEO

Keyword(s):

Ring Contraction ◽

Acid Catalyzed

Download Full-text

ChemInform Abstract: Hydroxyiminoisoquinolin-3(2H)-ones. Part 8. Acid-Catalyzed Ring Contraction and Semmler-Wolff Type Rearrangement.

ChemInform ◽

10.1002/chin.198901168 ◽

1989 ◽

Vol 20 (1) ◽

Author(s):

I. TIKK ◽

G. DEAK ◽

J. TAMAS

Keyword(s):

Ring Contraction ◽

Acid Catalyzed

Download Full-text

Acid-catalyzed Ring Contraction of Dibenzothiepin-10,11-dione

Angewandte Chemie International Edition in English ◽

10.1002/anie.196801281 ◽

1968 ◽

Vol 7 (2) ◽

pp. 128-129 ◽

Cited By ~ 5

Author(s):

A. Lüttringhaus ◽

G. Creutzburg

Keyword(s):

Ring Contraction ◽

Acid Catalyzed

Download Full-text

Acid-catalyzed reaction of 3-aminopyrrole with s-tetrazines: formation of 1H-1,2,4-(triazol-3-yl)pyrimidines via an unprecedented s-tetrazine-ring contraction and concomitant pyrrole-ring expansion

Tetrahedron Letters ◽

10.1016/j.tetlet.2014.08.004 ◽

2014 ◽

Vol 55 (40) ◽

pp. 5491-5494 ◽

Cited By ~ 5

Author(s):

Michael De Rosa ◽

David Arnold ◽

Hemant Yennawar

Keyword(s):

Pyrrole Ring ◽

Ring Expansion ◽

Ring Contraction ◽

Acid Catalyzed

Download Full-text

ChemInform Abstract: Derivatives of C-6 Functionalized 4-Heteroalkanals. Part 5. Influence of the Reaction Temperature on Some Acid-Catalyzed Processes of 6-Hydroxy-4-oxa-alkanal Derivatives and Related Products. Ring Contraction in 5-Alkoxy-1,4-dioxepane

ChemInform ◽

10.1002/chin.198739159 ◽

1987 ◽

Vol 18 (39) ◽

Author(s):

A. ESPINOSA ◽

M. A. GALLO ◽

J. CAMPOS ◽

A. ENTRENA

Keyword(s):

Reaction Temperature ◽

Ring Contraction ◽

Acid Catalyzed ◽

Derivatives Of

Download Full-text

Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones

Chemical Communications ◽

10.1039/c8cc07571a ◽

2018 ◽

Vol 54 (96) ◽

pp. 13547-13550 ◽

Cited By ~ 7

Author(s):

Stefania Porcu ◽

Alberto Luridiana ◽

Alberto Martis ◽

Angelo Frongia ◽

Giorgia Sarais ◽

...

Keyword(s):

Carbonyl Compounds ◽

General Strategy ◽

Reaction Sequence ◽

Ring Contraction ◽

Acid Catalyzed ◽

High Yields ◽

Ring Contraction Reaction

A general strategy for the synthesis of arylthio cyclopropyl carbaldehydes and ketones via acid catalysed arylthiol addition/ring contraction reaction sequence has been exploited. The procedure led to a wide panel of cyclopropyl carbonyl compounds in high yields and broad substrate scope.

Download Full-text