scholarly journals XXXVIII.—The study of binary mixtures. Part IV. Heats of reaction and specific heats

1916 ◽  
Vol 109 (0) ◽  
pp. 496-519 ◽  
Author(s):  
Arthur Bramley
Keyword(s):  
Binary Mixtures ◽  
Specific Heats ◽  
Heats Of Reaction

Volumes and Heat Capacities of Dimethylsulfoxide, Acetone, and Acetamide in Water and of some Electrolytes in these Mixed Aqueous Solvents

1975 ◽  
Vol 53 (21) ◽  
pp. 3263-3268 ◽  
Author(s):  
Osamu Kiyohara ◽  
Gèrald Perron ◽  
Jacques E. Desnoyers
Keyword(s):  
Binary Mixtures ◽  
Transfer Functions ◽  
Mixed Solvents ◽  
Water Structure ◽  
Heat Capacities ◽  
Ternary Mixtures ◽  
Specific Heats ◽  
Solute Interactions ◽  
Molal Volumes ◽  
Mixed Aqueous Solvents

The densities and volumetric specific heats of binary mixtures of dimethylsulfoxide (DMSO), acetone (ACT), and acetamide (ACM) in water were measured at 25 °C with a flow densimeter and a flow microcalorimeter. The same properties were also determined for ternary mixtures of 0.1 m LiCl, NaCl, Me4NBr, and Bu4NBr in ACT–water and DMSO–water mixtures, and volumes for 0.1 m Bu4NBr in ACM–water and urea–water mixtures. The derived apparent molal volumes and heat capacities of nonelectrolytes in water and the transfer functions of the electrolytes from water to the mixed solvents suggest that, contrary to urea, the present non-electrolytes are slightly hydrophobic but, with the possible exception of ACT, their overall influence on water structure has practically no influence on the various solute–solute interactions.

THE SPECIFIC HEATS OF BINARY MIXTURES

1925 ◽  
Vol 47 (6) ◽  
pp. 1490-1503 ◽  
Author(s):  
John Warren Williams ◽  
Farrington Daniels
Keyword(s):  
Binary Mixtures ◽  
Specific Heats

Thermodynamic properties of binary mixtures containing thiaalkanes

1980 ◽  
Vol 77 ◽  
pp. 445-449 ◽  
Author(s):  
Zohra Ferhat-Hamida ◽  
Robert Philippe ◽  
Jean-Claude Merlin ◽  
V. Kehiaian
Keyword(s):  
Thermodynamic Properties ◽  
Binary Mixtures
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