scholarly journals Unravelling the water adsorption in a robust iron carboxylate metal–organic framework

2020 ◽  
Vol 56 (67) ◽  
pp. 9628-9631
Author(s):  
Dirk Lenzen ◽  
Jakob G. Eggebrecht ◽  
Paulo G. M. Mileo ◽  
Dominik Fröhlich ◽  
Stefan Henninger ◽  
...  
Keyword(s):  
Water Adsorption ◽  
Metal Organic Framework ◽  
Scale Up ◽  
Molecular Simulations ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Iron Carboxylate ◽  
Organic Framework

Scale-up of an Fe-MOF and elucidation of its water adsorption properties by PXRD, sorption measurements and molecular simulations are reported.

Tailoring the water adsorption properties of MIL-101 metal–organic frameworks by partial functionalization

2015 ◽  
Vol 3 (5) ◽  
pp. 2057-2064 ◽  
Author(s):  
Nakeun Ko ◽  
Pan Gyu Choi ◽  
Jisu Hong ◽  
Miso Yeo ◽  
Siyoung Sung ◽  
...  
Keyword(s):  
Water Uptake ◽  
Water Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Low Pressure ◽  
Adsorption Properties ◽  
Uptake Capacity ◽  
Water Uptake Capacity ◽  
Metal Organic ◽  
Organic Framework

Partial functionalization of the metal–organic framework, MIL-101, with –COOH groups is proven effective for enhancing the water uptake capacity at low pressure.

Hazard Evaluation of Metal–Organic Framework Synthesis and Scale-up: A Laboratory Safety Perspective

2021 ◽  
Author(s):  
Harold U. Escobar-Hernandez ◽  
Ruiqing Shen ◽  
Maria I. Papadaki ◽  
Joshua A. Powell ◽  
Hong-Cai Zhou ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Scale Up ◽  
Hazard Evaluation ◽  
Laboratory Safety ◽  
Metal Organic ◽  
Organic Framework

Low-coverage adsorption properties of the metal–organic framework MIL-47 studied by pulse chromatography and Monte Carlo simulations

2009 ◽  
Vol 11 (18) ◽  
pp. 3515 ◽  
Author(s):  
Vincent Finsy ◽  
Sofia Calero ◽  
Elena García-Pérez ◽  
Patrick J. Merkling ◽  
Gill Vedts ◽  
...  
Keyword(s):  
Monte Carlo ◽  
Monte Carlo Simulations ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Low Coverage ◽  
Organic Framework

A 9-connected metal–organic framework with gas adsorption properties

2011 ◽  
Vol 21 (40) ◽  
pp. 15909 ◽  
Author(s):  
Guojian Ren ◽  
Shuxia Liu ◽  
Fengji Ma ◽  
Feng Wei ◽  
Qun Tang ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Organic Framework

A novel zinc(ii) metal–organic framework with a diamond-like structure: synthesis, study of thermal robustness and gas adsorption properties

2016 ◽  
Vol 45 (3) ◽  
pp. 1233-1242 ◽  
Author(s):  
Miroslav Almáši ◽  
Vladimír Zeleňák ◽  
Arnošt Zukal ◽  
Juraj Kuchár ◽  
Jiří Čejka
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Clapeyron Equation ◽  
Structure Synthesis ◽  
Metal Organic ◽  
Organic Framework

A novel 3D metal–organic framework with a diamond-like structure has been synthesised and structurally characterized. Adsorption of Ar, CO2, H2 and N2 has been studied. Heats of CO2 and H2 adsorption were calculated according to the Clausius–Clapeyron equation.

scholarly journals Facile stabilization of a cyclodextrin metal–organic framework under humid environment via hydrogen sulfide treatment

RSC Advances ◽  
2019 ◽  
Vol 9 (32) ◽  
pp. 18271-18276 ◽  
Author(s):  
Duo Ke ◽  
Jun-Feng Feng ◽  
Di Wu ◽  
Jun-Bo Hou ◽  
Xiao-Qin Zhang ◽  
...  
Keyword(s):  
Hydrogen Sulfide ◽  
Water Adsorption ◽  
Metal Organic Framework ◽  
Moisture Resistance ◽  
Adsorption Sites ◽  
Humid Environment ◽  
Metal Organic ◽  
Metal Ligand ◽  
Organic Framework

The moisture stable γ-CD-K-MOF was obtained by simply treating MOF with H2S gas. H2S acting as new water adsorption sites protected the metal–ligand bonds from water attack and thus enhanced the moisture resistance of γ-CD-K-MOF.

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