On the supramolecular properties of neutral, anionic and cationic cadmium complexes harvested from dithiolate–polyamine binary ligand systems

CrystEngComm ◽  
2020 ◽  
Vol 22 (46) ◽  
pp. 8023-8035
Author(s):  
Suman Adhikari ◽  
Tirtha Bhattacharjee ◽  
Arijit Das ◽  
Subhadip Roy ◽  
Constantin Gabriel Daniliuc ◽  
...  
Keyword(s):  
Cadmium Complexes

Three Cd(ii) complexes [Cd(i-mnt)(DMSO)2]n (1), {[Cd(i-mnt)pn]·2H2O} (2), and [Cd(i-mnt)3][Cd(tren)2]2 (3) harvested from 1,1-dicyanoethylene-2,2-dithiolate (i-mnt2−) and polyamine ligand systems have been designed, synthesized and structurally characterized.

Solution multinuclear (31P,111Cd,77Se) magnetic resonance studies of cadmium complexes of heterocyclic aromatic thiones and the structure of [tetrakis(2(1H)-pyridinethione)cadmium] nitrate, [Cd(C5H5NS)4](NO3)2

2000 ◽  
Vol 78 (5) ◽  
pp. 590-597 ◽  
Author(s):  
Umarani Rajalingam ◽  
Philip AW Dean ◽  
Hilary A Jenkins
Keyword(s):  
Cadmium Nitrate ◽  
Cadmium Complexes ◽  
Nmr Studies ◽  
X Ray ◽  
X Ray Crystallography ◽  
Stoichiometric Reaction ◽  
Complex Salts ◽  
Reduced Temperature ◽  
Aromatic Heterocyclic ◽  
Phosphine Chalcogenides

The complex salts CdL4(O3SCF3)2 (L = 2(1H)-pyridinethione (Py2SH), 4(1H)-pyridinethione (Py4SH), or 2(1H)-quinolinethione (Q2SH)) have been synthesized by the stoichiometric reaction of Cd(O3SCF3)2 and the appropriate thione. Both ambient-temperature 13C and reduced-temperature 111Cd NMR of CdL4(O3SCF3)2 in solution are consistent with L being bound through sulfur. Reduced-temperature NMR (31P, 77Se, 111Cd, as appropriate) of mixtures of CdL4(O3SCF3)2 and Cd(EPCy3)4(O3SCF3)2 (E = Se, Cy = c-C6H11) and of Cd(EPCy3)4(O3SCF3)2 (E = S, Se) and L in solution provides evidence for various [CdLn(EPCy3)4-n]2+. Similarly, reduced-temperature metal NMR of [CdL4]2+ and [CdL'4]2+ (L, L' = Py2SH, Py4SH, Q2SH; L not equal L') in solution shows the formation of [CdLnL'4-n]2+. Thus it has been demonstrated that at reduced temperature [CdL4]2+ is intact in solution and exchange of L is slow on the timescale of the metal chemical shift differences. From the NMR studies of Cd(EPCy3)4(O3SCF3)2 (E = S, Se):L mixtures, the binding preferences are found to be L > EPCy3 in solution. Similarly, from the reduced temperature metal NMR spectra of mixtures where L and L' compete for Cd(II) in solution, the binding preferences are Py4SH > Py2SH > Q2SH. The structure of Cd(Py2SH)4(NO3)2 (4) has been determined by single crystal X-ray analysis. Colorless crystals of 4 are tetragonal, I4(1)/acd with 8 molecules per unit cell of dimensions a = 18.660(3), c = 15.215(3) Å. The structure is comprised of recognizable NO3- anions and [Cd(Py2SH)4]2+ cations. In the cations, which have S4 symmetry, the ligands are S-bound. A network of NH···O hydrogen bonds links the cations and anions.Key words: aromatic heterocyclic thiones, cadmium complexes, phosphine chalcogenides, 111Cd, 31P, 77Se NMR, X-ray crystallography.

Three green luminescent cadmium complexes containing 8-aminoquinoline ligands: Syntheses, crystal structures, emission spectra and DFT calculations

2008 ◽  
Vol 128 (10) ◽  
pp. 1665-1672 ◽  
Author(s):  
Heng Xu ◽  
Liang-Fang Huang ◽  
Li-Min Guo ◽  
Yuan-Guang Zhang ◽  
Xiao-Ming Ren ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Crystal Structures ◽  
Emission Spectra ◽  
Cadmium Complexes

Syntheses and Characterizations of Two New Cadmium Complexes Based on Oxalate

2015 ◽  
Vol 36 (9) ◽  
pp. 2260-2266
Author(s):  
Ming-San Miao ◽  
Bo-Lin Cheng ◽  
Zhen Liang ◽  
Huai-Xia Yang ◽  
Xiang-Ru Meng
Keyword(s):  
Cadmium Complexes

scholarly journals Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2(X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments

2013 ◽  
Vol 57 (4) ◽  
pp. 447-454 ◽  
Author(s):  
Mohammad Hakimi ◽  
Zahra Mardani ◽  
Keyvan Moeini
Keyword(s):  
Cadmium Complexes

scholarly journals Labile synthetic cadmium complexes are not bioavailable to Pseudokirchneriella subcapitata in resin buffered solutions

2012 ◽  
Vol 124-125 ◽  
pp. 66-71 ◽  
Author(s):  
L. Verheyen ◽  
R. Merckx ◽  
E. Smolders
Keyword(s):  
Pseudokirchneriella Subcapitata ◽  
Cadmium Complexes

Channels, transporters and receptors for cadmium and cadmium complexes in eukaryotic cells: myths and facts

BioMetals ◽  
2019 ◽  
Vol 32 (3) ◽  
pp. 469-489 ◽  
Author(s):  
Frank Thévenod ◽  
Johannes Fels ◽  
Wing-Kee Lee ◽  
Ralf Zarbock
Keyword(s):  
Eukaryotic Cells ◽  
Cadmium Complexes

Dynamic features of the ethylenediaminetetraacetate complexes in aqueous solutions studied by the ultrasonic absorption method. 2. Zinc and cadmium complexes

1982 ◽  
Vol 104 (20) ◽  
pp. 5325-5328 ◽  
Author(s):  
Yoshinori Funaki ◽  
Shoji Harada ◽  
Kazuhiro Okumiya ◽  
Tatsuya Yasunaga
Keyword(s):  
Aqueous Solutions ◽  
Ultrasonic Absorption ◽  
Absorption Method ◽  
Dynamic Features ◽  
Cadmium Complexes
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