The use of main-group elements to mimic catalytic behavior of transition metals I: reduction of dinitrogen to ammonia catalyzed by bis(Lewis base)borylenium diradicals

2020 ◽  
Vol 22 (48) ◽  
pp. 28423-28433
Author(s):  
Yu Wang ◽  
Chun-Guang Liu
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Lewis Base ◽  
Main Group Elements ◽  
Catalytic Behavior ◽  
Metal Free

An emerging class of compounds, bis(Lewis base)borylenium diradicals with an electron-rich boron(i) center, are potential metal-free catalysts for dinitrogen activation and reduction.

Multiple Bonds between Transition Metals and Main-Group Elements. 142. Lewis-Base Adducts of Organorhenium(VII) Oxides: Structures and Dynamic Behavior in Solution

1995 ◽  
Vol 34 (11) ◽  
pp. 2914-2920 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Fritz E. Kuehn ◽  
Monika U. Rauch ◽  
Joao D. G. Correia ◽  
Georg Artus
Keyword(s):  
Transition Metals ◽  
Dynamic Behavior ◽  
Main Group ◽  
Lewis Base ◽  
Multiple Bonds ◽  
Main Group Elements

ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 84. Organoosmium Oxides: Efficient Syntheses and Structures.

ChemInform ◽  
2010 ◽  
Vol 22 (10) ◽  
pp. no-no
Author(s):  
W. A. HERRMANN ◽  
S. J. EDER ◽  
P. KIPROF ◽  
K. RYPDAL ◽  
P. WATZLOWIK
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements

ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 35. First Four-Membered Metallacycles of Rhenium.

ChemInform ◽  
1987 ◽  
Vol 18 (18) ◽  
Author(s):  
H. J. R. DE BOER ◽  
B. J. J. VAN DE HEISTEEG ◽  
M. FLOEEL ◽  
W. A. HERRMANN ◽  
O. S. AKKERMAN ◽  
...  
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements

Multiple Bonds between Main-Group Elements and Transition Metals. 135. Oxorhenium(V) Catalysts for the Olefination of Aldehydes

1994 ◽  
Vol 13 (11) ◽  
pp. 4531-4535 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Peter W. Roesky ◽  
Mei Wang ◽  
Wolfgang Scherer
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements

Methylene Addition to Multiple Bonds Between Ligand-Free Main Group Elements and Transition Metals ? A General Reaction

1983 ◽  
Vol 22 (S12) ◽  
pp. 1543-1557 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Josef Weichmann ◽  
Ulrich K�sthardt ◽  
Adolf Sch�fer ◽  
Rolf H�rlein ◽  
...  
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
General Reaction ◽  
Main Group Elements ◽  
Ligand Free
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