Carbonyl group and carbon dioxide activation by rare-earth-metal complexes

2020 ◽  
Vol 49 (48) ◽  
pp. 17472-17493
Author(s):  
Uwe Bayer ◽  
Reiner Anwander

Not just hilariously effective baits! Rare-earth-metal compounds selectively react with aldehydes, ketones and carbon dioxide to generate isolable compounds as crucial intermediates in organic synthesis and homogenous catalysis.

2021 ◽  
Author(s):  
Jun Cheng ◽  
Chengrong Lu ◽  
Bei Zhao

A series of rare earth metal complexes (Sm (1), Eu(2), Y(3), Yb(4), Lu(5)) based on Trost ligand were synthesized and well characterized, which catalyzed the cycloaddition of carbon dioxide and...


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