Multifunctional properties of {CuII2LnIII2} systems involving nitrogen-rich nitronyl nitroxide: single-molecule magnet behavior, luminescence, magnetocaloric effects and heat capacity

2021 ◽  
Author(s):  
Hongdao Li ◽  
Pei Jing ◽  
Jiao Lu ◽  
Lu Xi ◽  
Qi Wang ◽  
...  

A family of 3d–4f heterometallic ring-shaped clusters on the basis of a nitrogen-rich nitronyl nitroxide radical have been obtained, and they feature polyfunctionality including magnetic properties, thermodynamics and luminescence behavior.

2015 ◽  
Vol 44 (13) ◽  
pp. 6118-6125 ◽  
Author(s):  
Lei-Lei Li ◽  
Shuang Liu ◽  
Yuan Zhang ◽  
Wei Shi ◽  
Peng Cheng

Three new mononuclear tri-spin Ln-NITR compounds were synthesized and characterized in which the TbIII compound exhibits field-induced single-molecule magnet behaviour.


2021 ◽  
Vol 9 (1) ◽  
pp. 294-302
Author(s):  
Hongdao Li ◽  
Lu Xi ◽  
Pei Jing ◽  
Jianke Tang ◽  
Qi Wang ◽  
...  

Two Ln–radical one-dimensional chains have been isolated via a quinoline nitronyl nitroxide radical and the magnetic properties, thermodynamics and optical behavior of compounds were observed, exhibiting polyfunctionality of the 2p–4f system.


2019 ◽  
Vol 58 (21) ◽  
pp. 14285-14288 ◽  
Author(s):  
Jian Yun Shi ◽  
Ming Ze Wu ◽  
Peng Yun Chen ◽  
Ting Li ◽  
Li Tian ◽  
...  

2019 ◽  
Vol 48 (15) ◽  
pp. 4774-4778 ◽  
Author(s):  
Hao Miao ◽  
Miao Li ◽  
Hong-Qing Li ◽  
Fu-Xing Shen ◽  
Yi-Quan Zhang ◽  
...  

A new bis-tridentate nitronyl nitroxide radical was synthesized and characterized. Field-induced slow magnetic relaxation was observed in the radical-bridged CoII complex.


2017 ◽  
Vol 46 (31) ◽  
pp. 10452-10461 ◽  
Author(s):  
Jian Wang ◽  
Hao Miao ◽  
Zhao-Xin Xiao ◽  
Yan Zhou ◽  
Lin-Dan Deng ◽  
...  

A series of lanthanide complexes of the pyrimidyl-substituted nitronyl nitroxide radical have been synthesized and characterized structurally and magnetically.


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