scholarly journals Alkoxy-functionalized ionic liquid electrolytes: understanding ionic coordination of calcium ion speciation for the rational design of calcium electrolytes

2020 ◽  
Vol 13 (8) ◽  
pp. 2559-2569
Author(s):  
Xinpei Gao ◽  
Xu Liu ◽  
Alessandro Mariani ◽  
Giuseppe Antonio Elia ◽  
Manuel Lechner ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Calcium Ion ◽  
Rational Design ◽  
Proof Of Concept ◽  
Functionalized Ionic Liquid ◽  
Liquid Electrolytes

The proof-of-concept demonstration of a rechargeable Ca/V2O5 cell is given, taking advantage of an alkoxy-functionalized ionic liquid-based electrolyte enabling the displacement of the anions from the coordination of the Ca2+ cations.

Ether-functionalized ionic liquid electrolytes for lithium-air batteries

2013 ◽  
Vol 243 ◽  
pp. 19-23 ◽  
Author(s):  
Hirofumi Nakamoto ◽  
Yushi Suzuki ◽  
Taishi Shiotsuki ◽  
Fuminori Mizuno ◽  
Shougo Higashi ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Functionalized Ionic Liquid ◽  
Liquid Electrolytes ◽  
Lithium Air Batteries

Rational Design of Amperometric Gas Sensors with Ionic Liquid Electrolytes

2014 ◽  
Vol 64 (1) ◽  
pp. 95-103 ◽  
Author(s):  
M. T. Carter ◽  
J. R. Stetter ◽  
M. W. Findlay ◽  
V. Patel
Keyword(s):  
Ionic Liquid ◽  
Gas Sensors ◽  
Rational Design ◽  
Liquid Electrolytes

Sulfur-Mediated Reactions through Sulfonium Salts and Ylides

Synlett ◽  
2021 ◽  
Author(s):  
Pingfan Li
Keyword(s):  
Transition Metal ◽  
Rational Design ◽  
Acid Catalysis ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Bronsted Acid ◽  
Proof Of Concept ◽  
Sulfonium Salts ◽  
Brönsted Acid ◽  
Sulfonium Ylides

AbstractThis Account discusses several new reaction methods developed in our group that utilize sulfur-mediated reactions through sulfonium salts and ylides, highlighting the interplay of rational design and serendipity. Our initial goal was to convert aliphatic C–H bonds into C–C bonds site-selectively, and without the use of transition-metal catalysts. While a proof-of-concept has been achieved, this target is far from being ideally realized. The unexpected discovery of an anti-Markovnikov rearrangement and subsequent studies on difunctionalization of alkynes were much more straightforward, and eventually led to the new possibility of asymmetric N–H insertion of sulfonium ylides through Brønsted acid catalysis.1 Introduction2 Allylic/Propargylic C–H Functionalization3 Anti-Markovnikov Rearrangement4 Difunctionalization of Alkynes5 Asymmetric N–H Insertion of Sulfonium Ylides6 Conclusion

Modular Platform for Synthesis of Poly(Ionic Liquid) Electrolytes for Electrochemical Applications in Supercapacitors

2021 ◽  
Vol 6 (15) ◽  
pp. 3795-3801
Author(s):  
Radostina Kalinova ◽  
Ivaylo Dimitrov ◽  
Christo Novakov ◽  
Svetlana Veleva ◽  
Antonia Stoyanova
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolytes ◽  
Electrochemical Applications ◽  
Modular Platform ◽  
Poly Ionic Liquid
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