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Published By The Electrochemical Society

1938-5862, 1938-6737

2021 ◽  
Vol 105 (1) ◽  
pp. 247-258
Author(s):  
Serhii Dubinevych ◽  
Viacheslav Zinin ◽  
Volodymyr Redko ◽  
Boris A Blyuss ◽  
Elena Shembel ◽  
...  

Importance of lithium power sources is confirmed by the fact that on October 10, 2019, the Nobel Prize in Chemistry in 2019 was awarded for the development of lithium-ion batteries. 10 years earlier, in 2010,physicists Andre Geim and Kostya Novoselov were awarded the Nobel Prize in Physics "For groundbreaking experiments regarding the two dimensional material graphene". A synergistic effect of theory and practicality in the area of lithium batteries, and the theory and practicality in the field of graphene materials creates the unique possibility generate the innovative high-energy Li batteries based on the graphene materials.


2021 ◽  
Vol 105 (1) ◽  
pp. 329-337
Author(s):  
David Kusmič ◽  
Lenka Klakurková ◽  
Martin Julis ◽  
Pavel Gejdoš ◽  
Jindrich Vilis ◽  
...  

In this paper, commercially cold-rolled and artificial aged EN AW 7075 T6 alloy has been used. To ensure increased corrosion resistance, surface hardness, scratching resistance, and aesthetic features, this aluminium alloy was subsequently hard anodised and hot-water sealed (AC-A). The hard anodizing and sealing process increased surface hardness up to 304±13 HV 1 from an initial surface hardness of 194±3 HV 1. Also, the microhardness of the anodised layer and bulk material has been documented. Scanning electron microscopy (SEM) was used for microstructure and trapped precipitates investigation in the 42.9±1.4 thick formed anodised layer investigation. The T6 treated (AC) and hard anodised together with sealed (AC-A) EN AW 7075 alloy corrosion properties were evaluated using the anodic potentiodynamic polarisation tests (PPT) in a neutral 2.5% NaCl deaerated solution. The corrosion rate CR (mm/y) decreased approx. 39-times for the hard anodised and sealed EN AW 7075 alloy (AC-A), associated with the shift of the Ecorr (mV) to more positive values, degreased Icorr (µA) and increased Rp (Ohm) values compared to the artificial aged (AC) alloy. Additionally, the pitting was evaluated using laser confocal microscopy, and the pitting coefficient was also calculated.


2021 ◽  
Vol 105 (1) ◽  
pp. 29-34
Author(s):  
Elena Shembel ◽  
Yuliya Polishchuk ◽  
Volodymyr Kyrychenko ◽  
Volodymyr Redko ◽  
Boris A Blyuss ◽  
...  

The goal of this investigation is connected with wishes to use the melanin for formulating the solid polymer electrolyte without the binder for Li batteries. Nature and properties of solid polymer electrolyte of the Li batteries is an important factor for ensuring the properties of Li batteries. For successful optimization the properties of Li batteries the following list includes the important requirements for the polymer electrolyte: high conductivity in wide operating temperature, chemical stability and no ignition at under high temperature - even more than 1000C, low impedance of interface between electrode and solid polymer electrolyte, special design of system - the solid polymer electrolyte in porous structure of electrode. For developing the solid polymer electrolyte without the binder we fulfill this goal includes the melanin in the solid polymer electrolyte.


2021 ◽  
Vol 105 (1) ◽  
pp. 119-134
Author(s):  
Jana Zimáková ◽  
Petr Baca ◽  
Martin Langer ◽  
Tomáš Binar

This work deals with lead-acid batteries, their properties and individual types that are available on the market. The temperature dependences of the battery parameters at different ambient temperatures and at different discharging and charging modes are measured. 6 batteries are tested at different charging currents, which provides information about their behavior both during discharge and at the time of charging. During the experiments, testing is not only performed at room temperature, but the batteries are also exposed to high temperatures up to 75 °C.


2021 ◽  
Vol 105 (1) ◽  
pp. 467-473
Author(s):  
Marie Sedlarikova ◽  
Miroslav Zatloukal ◽  
Marek Bachmayer ◽  
Pavel Čudek

The topic of this work is the solution of the problem of biomaterials and biocompatibility of metallic materials. The following is a procedure for the production of samples and the study of corrosion processes in various environments.


2021 ◽  
Vol 105 (1) ◽  
pp. 355-369
Author(s):  
Tomáš Binar ◽  
Jana Zimáková ◽  
Jakub Steiniger ◽  
Lukáš Řehořek ◽  
Petr Křivík ◽  
...  

A layer of copper was applied to the base aluminum material using the cold spray method (cold kinetic deposition). The samples were exposed to corrosion in a salt chamber for 100, 200 and 300 hours. The change in the size of the internal and surface resistance of the samples was monitored. The corrosion results were also examined using an electron microscope.


2021 ◽  
Vol 105 (1) ◽  
pp. 441-452
Author(s):  
Katharina Mairhofer ◽  
Bettina Kipper-Pires ◽  
Gerhard Leitner ◽  
Guenter Fafilek

Well-defined cuprous oxide (Cu2O) thin films can be electrodeposited from an electrolyte containing copper (II) sulfate, lactic acid and sodium hydroxide. As Cu2O is a p-type semiconductor, it is possible to accelerate the process through illumination with light of sufficient energy (>2.1eV). Cyclic voltammetry and transient potentiostatic measurements were performed in a three-electrode setup with copper metalized wafers as a working electrode. Illumination was performed through the electrolyte, therefore absorption of light by the electrolyte had to be taken into consideration. Potentiostatic measurements with a blue LED as a light source have shown an tenfold increase in layer thickness in comparison to depositions without additional illumination. The deposited films were investigated with SEM analysis.


2021 ◽  
Vol 105 (1) ◽  
pp. 431-440
Author(s):  
Pavel Šafl ◽  
Jana Zimáková ◽  
Tomáš Binar

The aim of this work is to study the climatic influences on 3D printed materials. This study focuses on the HIPS material, which was chosen as the starting material for further studies. The material in the field of 3D printing is known for its rapid photooxidation, which results in the formation of cracks in the final product. A climatic chamber was used for degradation, in which UV light, heat and increased humidity were applied to the material. The degree of degradation was then checked by tensile test and electron microscope.


2021 ◽  
Vol 105 (1) ◽  
pp. 209-217
Author(s):  
Yuliya Polishchuk ◽  
Elena Shembel ◽  
Volodymyr Kyrychenko ◽  
Andrea Strakova Fedorkova ◽  
Volodymyr Redko ◽  
...  

Dynamics of change in impedance spectra and electrochemical parameters of the Li-S rechargeable batteries with non-aqueous liquid electrolyte 0.7 M LiIm, 0.25 M LiNO3, DME: DOL (2:1) during storage after assembly and cycling have been shown. For modification of the Sulfur cathode, we used the different types of melanin. Our results confirm that melanin can be used as a promising component of sulfur-based electrodes


2021 ◽  
Vol 105 (1) ◽  
pp. 575-587
Author(s):  
Tomáš Binar ◽  
Jana Zimáková ◽  
Petr Baca ◽  
Jiri Fridrich ◽  
Marie Sedlarikova

This paper describes the design of mobile power sets for variable traffic signs for the use of energy storage in lead-acid battery. The supply point is intended primarily for use in powering traffic lights and mobile variable traffic signs for line traffic control. A test sample of the system was assembled, on which a series of measurements were performed to verify its functionality.


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