Iridium-catalyzed C3-selective asymmetric allylation of 7-azaindoles with secondary allylic alcohols

2021 ◽  
Vol 57 (76) ◽  
pp. 9684-9687
Author(s):  
Takahiro Sawano ◽  
Takeshi Matsui ◽  
Marina Koga ◽  
Eri Ishikawa ◽  
Ryo Takeuchi
Keyword(s):  
Allylic Alcohols ◽  
Asymmetric Allylation

An Ir/chiral phosphoramidite complex catalyzes C3-selective asymmetric allylic allylation of 7-azaindoles with secondary racemic alcohols.

scholarly journals Synthesis and Application of Chiral Spiro Phospholane Ligand in Pd-Catalyzed Asymmetric Allylation of Aldehydes with Allylic Alcohols.

ChemInform ◽  
2005 ◽  
Vol 36 (43) ◽  
Author(s):  
Shou-Fei Zhu ◽  
Yun Yang ◽  
Li-Xin Wang ◽  
Bin Liu ◽  
Qi-Lin Zhou
Keyword(s):  
Allylic Alcohols ◽  
Asymmetric Allylation

Synthesis and Application of Chiral Spiro Phospholane Ligand in Pd-Catalyzed Asymmetric Allylation of Aldehydes with Allylic Alcohols

2005 ◽  
Vol 7 (12) ◽  
pp. 2333-2335 ◽  
Author(s):  
Shou-Fei Zhu ◽  
Yun Yang ◽  
Li-Xin Wang ◽  
Bin Liu ◽  
Qi-Lin Zhou
Keyword(s):  
Allylic Alcohols ◽  
Asymmetric Allylation

Active MnO2 As a Mild Oxidizing Reagent for the Controlled Oxidation of Benzylic and Allylic Alcohols

2012 ◽  
Vol 2 (6) ◽  
pp. 48-48
Author(s):  
Y. M. Nandurkar Y. M. Nandurkar ◽  
◽  
B. B. Bahule B. B. Bahule
Keyword(s):  
Allylic Alcohols

Bimetallic Radical Redox-Relay Catalysis for the Isomerization of Epoxides to Allylic Alcohols

2019 ◽  
Author(s):  
Ke-Yin Ye ◽  
Terry McCallum ◽  
Song Lin
Keyword(s):  
Ring Opening ◽  
High Reactivity ◽  
Hydrogen Atom Transfer ◽  
Organic Radicals ◽  
Epoxide Ring ◽  
Allylic Alcohols ◽  
Epoxide Ring Opening ◽  
Bond Forming ◽  
Co Catalysts ◽  
The Rich

Organic radicals are generally short-lived intermediates with exceptionally high reactivity. Strategically, achieving synthetically useful transformations mediated by organic radicals requires both efficient initiation and selective termination events. Here, we report a new catalytic strategy, namely bimetallic radical redox-relay, in the regio- and stereoselective rearrangement of epoxides to allylic alcohols. This approach exploits the rich redox chemistry of Ti and Co complexes and merges reductive epoxide ring opening (initiation) with hydrogen atom transfer (termination). Critically, upon effecting key bond-forming and -breaking events, Ti and Co catalysts undergo proton-transfer/electron-transfer with one another to achieve turnover, thus constituting a truly synergistic dual catalytic system.<br>

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