scholarly journals Exploration of Highly Electron-Rich Manganese Complexes in Enantioselective Oxidation Catalysis; a Focus on Enantioselective Benzylic Oxidation

2021 ◽  
Author(s):  
Eduard Masferrer-Rius ◽  
Fanshi Li ◽  
Martin Lutz ◽  
Robertus J.M. Klein Gebbink
Keyword(s):  
Oxidation Catalysis ◽  
Manganese Complexes ◽  
Biologically Inspired ◽  
Enantioselective Oxidation ◽  
Benzylic Alcohols ◽  
Benzylic Oxidation

The direct enantioselective hydroxylation of benzylic C–H bonds to form chiral benzylic alcohols represents a challenging transformation. Herein, we report on the exploration of new biologically inspired manganese and iron...

scholarly journals Systematic ligand variation to modulate the electrochemical properties of iron and manganese complexes

2019 ◽  
Vol 48 (35) ◽  
pp. 13205-13211 ◽  
Author(s):  
Stefan S. Rohner ◽  
Niklas W. Kinzel ◽  
Christophe Werlé ◽  
Walter Leitner
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Properties ◽  
Electronic Properties ◽  
Water Oxidation ◽  
Oxidation Catalysis ◽  
Manganese Complexes ◽  
Catalytic Current ◽  
Water Oxidation Catalysis ◽  
Iron And Manganese

Systematic series of iron(+iii) and manganese(+ii) complexes are investigated by cyclic voltammetry to elucidate how the electronic properties of the ligands influence overpotential and catalytic current in the context of water oxidation catalysis.

Oxidation catalysis via visible-light water activation of a [Ru(bpy)3]2+ chromophore BSA–metallocorrole couple

2016 ◽  
Vol 45 (2) ◽  
pp. 706-710 ◽  
Author(s):  
Christian Herrero ◽  
Annamaria Quaranta ◽  
Rémy Ricoux ◽  
Alexandre Trehoux ◽  
Atif Mahammed ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Visible Light ◽  
Ruthenium Complex ◽  
Oxidation Catalysis ◽  
Light Water ◽  
Enantioselective Oxidation ◽  
Water Activation ◽  
Atom Source ◽  
Artificial Metalloenzyme

Light induced enantioselective oxidation of thioanisole with water as the oxygen atom source is catalyzed by a Mn-corrole–BSA artificial metalloenzyme in the presence of a photoactivable ruthenium complex.

Palladium/NHC-catalyzed tandem benzylic oxidation/oxidative esterification of benzylic alcohols with phenols

Tetrahedron ◽  
2011 ◽  
Vol 67 (33) ◽  
pp. 5878-5882 ◽  
Author(s):  
Fang Luo ◽  
Changduo Pan ◽  
Jiang Cheng ◽  
Fan Chen
Keyword(s):  
Oxidative Esterification ◽  
Benzylic Alcohols ◽  
Benzylic Oxidation

Biologically inspired oxidation catalysis

Nature ◽  
2008 ◽  
Vol 455 (7211) ◽  
pp. 333-340 ◽  
Author(s):  
Lawrence Que ◽  
William B. Tolman
Keyword(s):  
Oxidation Catalysis ◽  
Biologically Inspired
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