Palladium(II)-Catalyzed Aerobic Oxidative O-H/C-H Isocyanide Insertion: Facile Access to Pyrrolo[2,1-c][1,4]benzoxazine Derivatives

2021 ◽  
Author(s):  
Liangliang Luo ◽  
Xiao-Pan Chen ◽  
Zhao-Feng Li ◽  
Yuan Zhou ◽  
You-Cai Xiao ◽  
...  
Keyword(s):  
Oxidative Cyclizations ◽  
Palladium Catalyzed

Palladium-catalyzed aerobic oxidative cyclizations of substituted 2-(1H-pyrrol-1-yl)phenols with isocyanides via O-H/C-H insertion cascade have been developed. This strategy provides a facile access to pyrrolo[2,1-c][1,4]benzoxazine derivatives in good to excellent yields...

Palladium-Catalyzed Oxidative Cyclizations:  Synthesis of Dihydropyranones and Furanones

2005 ◽  
Vol 70 (21) ◽  
pp. 8478-8485 ◽  
Author(s):  
Maud Reiter ◽  
Hazel Turner ◽  
Rebecca Mills-Webb ◽  
Véronique Gouverneur
Keyword(s):  
Oxidative Cyclizations ◽  
Palladium Catalyzed

Recent Advances in Palladium-Catalyzed Oxidative Cyclizations

2019 ◽  
Vol 23 (9) ◽  
pp. 1019-1044
Author(s):  
John C. Hershberger
Keyword(s):  
Palladium Catalysis ◽  
Oxidative Cyclization ◽  
Heterocyclic Synthesis ◽  
Oxidative Cyclizations ◽  
The Past ◽  
Recent Advances ◽  
Palladium Catalyzed

Heterocycles are very common substructures in a number of pharmaceuticals. Over the past several years, the use of palladium-catalyzed oxidative cyclization for heterocyclic synthesis has become much more prevalent. This review collects recent reports using palladium catalysis to synthesize a wide variety of heterocyclic scaffolds. Many of these reactions use oxygen as the terminal oxidant. Some salient mechanistic features are discussed.

scholarly journals Palladium-Catalyzed Oxidative Cyclizations: Synthesis of Dihydropyranones and Furanones.

ChemInform ◽  
2006 ◽  
Vol 37 (9) ◽  
Author(s):  
Maud Reiter ◽  
Hazel Turner ◽  
Rebecca Mills-Webb ◽  
Veronique Gouverneur
Keyword(s):  
Oxidative Cyclizations ◽  
Palladium Catalyzed

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

Synthesis of Allenyl Ketones by the Palladium-Catalyzed Carbonylation of 2-Alkynyl Carbonates in the Presence of Soft Carbon Nucleophiles

Synlett ◽  
1991 ◽  
Vol 1991 (09) ◽  
pp. 697-698 ◽  
Author(s):  
Tadakatsu Mandai ◽  
Hiroaki Kunitomi ◽  
Kiyoto Higashi ◽  
Mikio Kawada ◽  
Jiro Tsuji
Keyword(s):  
Carbon Nucleophiles ◽  
Palladium Catalyzed ◽  
Soft Carbon
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