Domino Heck/Hiyama cross-coupling: trapping of the σ-alkylpalladium intermediate with arylsilanes

A Pd-catalyzed domino Heck cyclization/Hiyama cross-coupling sequence of aryl-tethered activated/unactivated alkenes with arylsilanes is described.

A New β-Carbolinone Synthesis Using a Rh(II)-Promoted [3 + 2]-Cycloaddition and Pd(0) Cross-Coupling/Heck Cyclization Chemistry.

ChemInform ◽

10.1002/chin.200409123 ◽

2004 ◽

Vol 35 (9) ◽

Author(s):

Joel M. Harris ◽

Albert Padwa

Keyword(s):

Cross Coupling ◽

Heck Cyclization

ChemInform Abstract: Palladium(0)-Catalyzed Thioboration of Terminal Alkynes with 9-( Alkylthio)-9-borabicyclo(3.3.1)nonane Derivatives: Stereoselective Synthesis of Vinyl Sulfides via the Thioboration-Cross-Coupling Sequence.

ChemInform ◽

10.1002/chin.199350124 ◽

2010 ◽

Vol 24 (50) ◽

pp. no-no

Author(s):

T. ISHIYAMA ◽

K. NISHIJIMA ◽

N. MIYAURA ◽

A. SUZUKI

Keyword(s):

Cross Coupling ◽

Terminal Alkynes ◽

Vinyl Sulfides ◽

Novel Methodology for the Efficient Synthesis of 3-Aryloxindoles: [1,2]-Phospha-Brook Rearrangement–Palladium-Catalyzed Cross-Coupling Sequence

Synlett ◽

10.1055/s-0035-1561859 ◽

2016 ◽

Vol 27 (12) ◽

pp. 1848-1853 ◽

Cited By ~ 5

Author(s):

Masahiro Terada ◽

Azusa Kondoh ◽

Akira Takei

Keyword(s):

Cross Coupling ◽

Efficient Synthesis ◽

Brook Rearrangement ◽

Palladium Catalyzed ◽

ChemInform Abstract: Carbon-Carbon Bond Formation of α-Alkynylzirconacyclopentenes via Cyclization or a Cu/Pd-Mediated Cyclization/Cross-Coupling Sequence with Aryl Iodides.

ChemInform ◽

10.1002/chin.200911070 ◽

2009 ◽

Vol 40 (11) ◽

Author(s):

Jingjin Chen ◽

Yuxue Li ◽

Hongjun Gao ◽

Yuanhong Liu

Keyword(s):

Bond Formation ◽

Cross Coupling ◽

Carbon Bond ◽

Aryl Iodides ◽

Carbon Carbon Bond ◽

Continuous-Flow Synthesis of Biaryls Enabled by Multistep Solid-Handling in a Lithiation/Borylation/Suzuki-Miyaura Cross-Coupling Sequence

Angewandte Chemie International Edition ◽

10.1002/anie.201105223 ◽

2011 ◽

Vol 50 (45) ◽

pp. 10665-10669 ◽

Cited By ~ 78

Author(s):

Wei Shu ◽

Laurent Pellegatti ◽

Matthias A. Oberli ◽

Stephen L. Buchwald

Keyword(s):

Continuous Flow ◽

Cross Coupling ◽

Flow Synthesis ◽

ChemInform Abstract: A One-Pot Synthesis of (E)-Disubstituted Alkenes by a Bimetallic [Rh—Pd]-Catalyzed Hydrosilylation/Hiyama Cross-Coupling Sequence.

ChemInform ◽

10.1002/chin.200809075 ◽

2008 ◽

Vol 39 (9) ◽

Author(s):

Carine Thiot ◽

Marc Schmutz ◽

Alain Wagner ◽

Charles Mioskowski

Keyword(s):

Cross Coupling ◽

One Pot ◽

One Pot Synthesis ◽

ChemInform Abstract: Stereoselective Synthesis of Exocyclic Alkenes via Hydroboration-Cross- Coupling Sequence.

ChemInform ◽

10.1002/chin.199244079 ◽

2010 ◽

Vol 23 (44) ◽

pp. no-no

Author(s):

N. MIYAURA ◽

M. ISHIKAWA ◽

A. SUZUKI

Keyword(s):

Cross Coupling ◽

A Three-Way Switchable Process for Suzuki Cross-Coupling, Hydrodehalogenation, or an Assisted Tandem Hydrodehalogenation and Suzuki Cross-Coupling Sequence

Advanced Synthesis & Catalysis ◽

10.1002/adsc.201300395 ◽

2013 ◽

Vol 355 (16) ◽

pp. 3231-3243 ◽

Cited By ~ 21

Author(s):

Alexander H. Sandtorv ◽

Hans-René Bjørsvik

Keyword(s):

Cross Coupling ◽

A stereoselective synthesis of 1,2-diarylethenyl ethyl ethers via the carbocupration-cross coupling sequence

Tetrahedron ◽

10.1016/0040-4020(96)00794-6 ◽

1996 ◽

Vol 52 (42) ◽

pp. 13347-13354 ◽

Cited By ~ 12

Author(s):

Noriyasu Kato ◽

Norio Miyaura

Keyword(s):

Cross Coupling ◽

ChemInform Abstract: Stereoselective Synthesis of 1,2-Diarylethenyl Ethyl Ethers via the Carbocupration-Cross Coupling Sequence.

ChemInform ◽

10.1002/chin.199705131 ◽

2010 ◽

Vol 28 (5) ◽

pp. no-no

Author(s):

N. KATO ◽

N. MIYAURA

Keyword(s):

Cross Coupling ◽