Carbene complexes. Part VI. Complexes from imidoyl chloride and rhodium(I) precursors, and the crystal and molecular structure of carbonyltri-iodo-[α-(N-methyl-α-methyliminobenzylamino)benzylidene-N,C]rhodium, I3(OC)Rh–CPh(NMe)CPh:NMe

Author(s):  
Peter B. Hitchcock ◽  
Michael F. Lappert ◽  
George M. McLaughlin ◽  
Andrew J. Oliver
2012 ◽  
Vol 67 (6) ◽  
pp. 509-518 ◽  
Author(s):  
Liliana Dobrzańska ◽  
Gerrit R. Julius ◽  
Elzet Stander-Grobler ◽  
Yolanda Burger (neé Stander) ◽  
Stefan D. Nogai ◽  
...  

Transmetallation and oxidative substitution were utilized to prepare examples of group 14, group 6 and group 10 complexes from lithiated or chlorinated 4,4-dimethyl-2-(2-thienyl) oxazoline or its N-alkylated analogs. Two of the product types (2and 5) can be classified as a-thio or remote carbene complexes, depending on the position (3- or 5-) of attachment to the substituted thiophene ring. Spectroscopic measurements as well as crystal and molecular structure determinations clarified the bonding within the new compounds.


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