Fluorocarbon complexes of the transition metals. Part III. Chemistry of tertiary arsine derivatives of tetrakis(trifluoromethyl)rhodacyclo-pentadiene

1975 ◽  
pp. 900 ◽  
Author(s):  
Joel T. Mague
Keyword(s):  
Transition Metals ◽  
Tertiary Arsine ◽  
Derivatives Of

Carbonyl halides of the Group VI transition metals. XI. Dithiocyanatocarbonyl derivatives of molybdenum and tungsten(II)

1968 ◽  
Vol 21 (6) ◽  
pp. 1435 ◽  
Author(s):  
R Colton ◽  
GR Scollary
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Ammonium Chloride ◽  
Pure State ◽  
Ammonium Thiocyanate ◽  
Donor Ligands ◽  
Group Vi ◽  
Derivatives Of ◽  
And Tungsten

Reaction of ammonium thiocyanate with dihalocarbonyls of molybdenum and tungsten(11) leads to the elimination of ammonium chloride and the formation of a dithiocyanatocarbonyl complex of the transition metal. Although the thiocyanatocarbonyls themselves have not been isolated in a pure state, a number of substituted derivatives with phosphorus donor ligands have been prepared and characterized. In general these complexes are less stable than the corresponding carbonyl halide derivatives.

Organometalloidal derivatives of the transition metals

1992 ◽  
Vol 430 (3) ◽  
pp. 273-286 ◽  
Author(s):  
Antonio Guerrero ◽  
Jacobo Gómez-Lara ◽  
Jorge Cervantes ◽  
Luis Velasco ◽  
Hemant Sharma ◽  
...  
Keyword(s):  
Transition Metals ◽  
Derivatives Of

ChemInform Abstract: NEW METHOD FOR SYNTHESIZING METALLOORGANIC DERIVATIVES OF TRANSITION METALS IN THE LOWEST DEGREES OF OXIDATION

1978 ◽  
Vol 9 (4) ◽  
Author(s):  
S. I. BEILIN ◽  
S. B. GOL'SHTEIN ◽  
B. A. DOLGOPLOSK ◽  
A. M. KRAPIVIN ◽  
E. I. TINYAKOVA ◽  
...  
Keyword(s):  
Transition Metals ◽  
New Method ◽  
Derivatives Of
Sign in / Sign up

Export Citation Format

Share Document