Synthesis and characterization of perovskite-phase mixed-metal oxides: lead titanate

1995 ◽  
Vol 5 (1) ◽  
pp. 151 ◽  
Author(s):  
Leo B. Archer ◽  
Clive D. Chandler ◽  
Richard Kingsborough ◽  
Mark J. Hampden-Smith
Keyword(s):  
Metal Oxides ◽  
Lead Titanate ◽  
Perovskite Phase ◽  
Synthesis And Characterization ◽  
Mixed Metal Oxides ◽  
Mixed Metal

Synthetic Routes to Perovskite Phase Mixed Metal Oxides

1991 ◽  
Vol 243 ◽  
Author(s):  
Clive D. Chandler ◽  
Mark J. Hampden-Smith ◽  
Jeffrey Brinker
Keyword(s):  
Metal Oxides ◽  
Lead Titanate ◽  
Perovskite Phase ◽  
Single Component ◽  
Mixed Metal Oxides ◽  
Reaction Conditions ◽  
Lead Carbonate ◽  
Mixed Metal ◽  
Loss Of Weight ◽  
Synthetic Routes

AbstractWe are developing strategies to form single-component precursors to perovskite phase mixed metal oxides where the stoichiometry of the precursor is fixed at the molecular level to be that of the final desired phase. These strategies ean be applied to the formation of perovskite phase thin films. Two such methods are described herein, relying on ester elimination and alcohol elimination reactions. We have found the reaction between lead(II) acetate and titanium(IV) isopropoxide in ethanol results in ligand redistribution at room temperature. Reactions between (β-diketonate)2M(OR)2 where M = Ti, Zr and Sn and lead(II) acetate do not result in any detectable ester elimination under the reaction conditions employed, and this approach was not successful. Alcohol elimination experiments have been explored as an alternative strategy using a bifunctional glycolate ligand. Lead carbonate reacted with glycolic acid to form the corresponding lead glycolate complex Pb(O2CCH2OH)2. This compound reacted with (β-diketonate)2M(OR)2, M = Ti and Sn, to eliminate two equivalents of alcohol and form the corresponding single component (β-diketonate)2M(OCH2CO2)2Pb complexes. These complexes start to thermally decompose at 150°C and loss of weight is complete by 450°C to yield a product whose weight loss corresponds to the formation of PbTiO3 for M = Ti. Bulk thermolysis of a sample of (dpm)2Ti(OCH2CO2)2Pb at 400°C resulted in formation of crystalline perovskite phase lead titanate together with PbO, massicot and α-PbO phases.

Semi-wet growth and characterization of multi-functional nano-engineered mixed metal oxides for industrial application

2021 ◽  
Vol 67 (4) ◽  
pp. 100542
Author(s):  
Laxman Singh ◽  
Ravikant Sharma ◽  
Narayan Singh ◽  
Atendra Kumar ◽  
Dev K Mahato ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Industrial Application ◽  
Mixed Metal Oxides ◽  
Mixed Metal

scholarly journals Preparation and characterization of ZnO/ZnAl2O4-mixed metal oxides for dye-sensitized photodetector using Zn/Al-layered double hydroxide as precursor

2019 ◽  
Vol 21 (3) ◽  
Author(s):  
Ethar Yahya Salih ◽  
Mohd Faizul Mohd Sabri ◽  
Sin Tee Tan ◽  
Khaulah Sulaiman ◽  
Mohd Zobir Hussein ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Layered Double Hydroxide ◽  
Mixed Metal Oxides ◽  
Mixed Metal ◽  
Dye Sensitized ◽  
Double Hydroxide
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