286. The liquid dinitrogen tetroxide solvent system. Part III. The electrical conductivity of liquid dinitrogen tetroxide

1951 ◽  
pp. 1289 ◽  
Author(s):  
C. C. Addison ◽  
J. Allen ◽  
H. C. Bolton ◽  
J. Lewis
Keyword(s):  
Electrical Conductivity ◽  
Solvent System ◽  
Dinitrogen Tetroxide ◽  
System Part

The chlorosulfuric acid solvent system. Part II. The solutes SeCl4 and TeCl4; evidence for the formation of the SeCl3+ and TeCl3+ ions

1968 ◽  
Vol 46 (20) ◽  
pp. 3197-3200 ◽  
Author(s):  
E. A. Robinson ◽  
J. A. Ciruna
Keyword(s):  
Electrical Conductivity ◽  
Raman Spectra ◽  
Vibrational Spectra ◽  
Strong Acid ◽  
Ionic Species ◽  
Solvent System ◽  
Acid Solutions ◽  
Conductivity Measurements ◽  
System Part

From the results of electrical conductivity measurements on solutions in chlorosulfuric acid and the Raman spectra of solutions in chlorosulfuric acid (and fluorosulfuric acid) it is shown that SeCl4 and TeCl4 ionize quantitatively in these strong acid solutions to give the SeCl3+ and TeCl3+ cations.By comparison of the spectra with the vibrational spectra of solid SeCl4 and solid TeCl4, reported by other workers, it is suggested that the solids contain covalent MCl4 molecules rather than the ionic species MCl3+•Cl−, suggested previously.

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