The biosynthesis of fungal metabolites. Part IV. Tajixanthone: 13C nuclear magnetic resonance spectrum and feedings with [1-13C]- and [2-13C]-acetate

Author(s):  
John S. E. Holker ◽  
Roy D. Lapper ◽  
Thomas J. Simpson
1972 ◽  
Vol 50 (12) ◽  
pp. 1975-1977 ◽  
Author(s):  
Larry Weiler

The 13C-n.m.r. spectrum of tropolone has been obtained and it clearly shows that there is a rapid tautomeric equilibrium at room temperature. The peaks have been tentatively assigned using calculated π charge densities and nuclear Overhauser enhancements.


Nature ◽  
1970 ◽  
Vol 227 (5260) ◽  
pp. 840-842 ◽  
Author(s):  
W. A. GIBBONS ◽  
J. A. SOGN ◽  
A. STERN ◽  
L. C. CRAIG ◽  
L. F. JOHNSON

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