Biosynthesis of malonomicin. Part 1. 13C nuclear magnetic resonance spectrum and feeding experiments with 13C-labelled precursors

Author(s):  
Dick Schipper ◽  
Juul L. van der Baan ◽  
Friedrich Bickelhaupt
1972 ◽  
Vol 50 (12) ◽  
pp. 1975-1977 ◽  
Author(s):  
Larry Weiler

The 13C-n.m.r. spectrum of tropolone has been obtained and it clearly shows that there is a rapid tautomeric equilibrium at room temperature. The peaks have been tentatively assigned using calculated π charge densities and nuclear Overhauser enhancements.


Nature ◽  
1970 ◽  
Vol 227 (5260) ◽  
pp. 840-842 ◽  
Author(s):  
W. A. GIBBONS ◽  
J. A. SOGN ◽  
A. STERN ◽  
L. C. CRAIG ◽  
L. F. JOHNSON

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