Electron spin resonance measurements of propagation and termination rate constants during the liquid-phase oxidation of hydrocarbons

1974 ◽  
pp. 797 ◽  
Author(s):  
John E. Bennett ◽  
John A. Eyre ◽  
Raymond Summers
Keyword(s):  
Electron Spin Resonance ◽  
Liquid Phase ◽  
Electron Spin ◽  
Rate Constants ◽  
Liquid Phase Oxidation ◽  
Termination Rate ◽  
Oxidation Of Hydrocarbons ◽  
Spin Resonance ◽  
Phase Oxidation

Effect of surfactants on liquid-phase oxidation of hydrocarbons and lipids

2008 ◽  
Vol 78 (8) ◽  
pp. 1533-1544 ◽  
Author(s):  
O. T. Kasaikina ◽  
Z. S. Kartasheva ◽  
L. M. Pisarenko
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Oxidation ◽  
Oxidation Of Hydrocarbons ◽  
Phase Oxidation

ChemInform Abstract: Catalysis and Inhibition by Water During the Liquid-Phase Oxidation of Hydrocarbons.

ChemInform ◽  
2010 ◽  
Vol 24 (38) ◽  
pp. no-no
Author(s):  
L. J. CSANYI ◽  
K. JAKY
Keyword(s):  
Liquid Phase ◽  
Liquid Phase Oxidation ◽  
Oxidation Of Hydrocarbons ◽  
Phase Oxidation

Direct measurement of diffusion in liquid phase by electron spin resonance

2008 ◽  
Vol 465 (1-3) ◽  
pp. 147-152 ◽  
Author(s):  
Aharon Blank ◽  
Yael Talmon ◽  
Michael Shklyar ◽  
Lazar Shtirberg ◽  
Wolfgang Harneit
Keyword(s):  
Electron Spin Resonance ◽  
Liquid Phase ◽  
Direct Measurement ◽  
Electron Spin ◽  
Spin Resonance

An Electron Spin Resonance Study of Some Reactions of Pentafluorosulfuranyl (SF5)

1975 ◽  
Vol 53 (16) ◽  
pp. 2361-2364 ◽  
Author(s):  
John Charles Tait ◽  
James Anthony Howard
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Rate Constants ◽  
Arrhenius Equation ◽  
Kinetic Studies ◽  
Electron Spin Resonance Study ◽  
Order Process ◽  
First Order ◽  
Spin Resonance ◽  
Spin Resonance Study

A kinetic electron spin resonance study of the self-reaction of SF5 and a spectroscopic and kinetic e.s.r. study of the reaction of SF5 with 1,1-di-t-butylethylene are reported. This radical undergoes self-reaction by a second-order process and the rate constants are given by the Arrhenius equation log 2k1(M−1 s−1) = (10.3 ± 0.5) − (1.7 ± 0.5)/θ where θ = 2.303RT kcal mol−1. It adds to 1,1-di-t-butylethylene to give (t-Bu)2CCH2SF5 which decomposes by a first-order process with rate constants that obey the expression log k2(s−1) = (13 ± 0.4) − (10 ± 0.2)/θ. Both these rate constants are pertinent to kinetic studies of the photoinduced addition of SF5C1 to olefins.

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