Addition of free radicals to unsaturated systems. Part 24. Kinetics and mechanism of the gas-phase thermal reactions of trifluoroiodomethane with propene

1983 ◽  
pp. 1713 ◽  
Author(s):  
Robert N. Haszeldine ◽  
David W. Keen ◽  
Peter J. Robinson
Keyword(s):  
Free Radicals ◽  
Gas Phase ◽  
Kinetics And Mechanism ◽  
Thermal Reactions

THE KINETICS OF THE THERMAL REACTIONS OF ETHYLENE OXIDE

1963 ◽  
Vol 41 (12) ◽  
pp. 2956-2961 ◽  
Author(s):  
M. Lynne Neufeld ◽  
Arthur T. Blades
Keyword(s):  
Free Radicals ◽  
Free Radical ◽  
Ethylene Oxide ◽  
Thermal Reactions ◽  
Kinetics Of

The thermal reactions of ethylene oxide in the presence of an excess of propylene have been studied as a function of pressure and it has been found that there are two sets of products, acetaldehyde and free radicals, presumably methyl and formyl. These products are believed to arise from an excited acetaldehyde intermediate. Some evidence has been obtained for the occurrence of a surface-catalyzed rearrangement to acetaldehyde but the free radical products are uninfluenced by surface.

μSr studies of free radicals in the gas phase

1995 ◽  
Vol 190 (2) ◽  
pp. 493-503 ◽  
Author(s):  
M. Senba ◽  
D. J. Arseneau ◽  
J. J. Pan ◽  
M. Shelley ◽  
D. G. Fleming
Keyword(s):  
Free Radicals ◽  
Gas Phase
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