Solute–solvent and solvent–solvent interactions in binary solvent mixtures. Part 1. A comparison of several preferential solvation models for describing ET(30) polarity of bipolar hydrogen bond acceptor-cosolvent mixtures

1995 ◽  
pp. 1607-1615 ◽  
Author(s):  
Marti Rosés ◽  
Clara Ràfols ◽  
José Ortega ◽  
Elisabeth Bosch
Keyword(s):  
Hydrogen Bond ◽  
Preferential Solvation ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Hydrogen Bond Acceptor ◽  
Solvent Interactions ◽  
Binary Solvent Mixtures ◽  
Solvation Models ◽  
Solvent Solvent ◽  
Cosolvent Mixtures

Preferential solvation of p-nitroaniline in a binary mixture of chloroform and hydrogen bond acceptor solvents: the role of specific solute–solvent hydrogen bonding

2020 ◽  
Vol 22 (6) ◽  
pp. 3545-3562 ◽  
Author(s):  
Prakash Kumar Malik ◽  
Madhusmita Tripathy ◽  
Aravind Babu Kajjam ◽  
Sabita Patel
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Binary Mixture ◽  
Preferential Solvation ◽  
Binary Solvent ◽  
Local Concentration ◽  
Solvent Mixtures ◽  
Hydrogen Bond Acceptor ◽  
Binary Solvent Mixtures

Solute–solvent H-bonding in binary solvent mixtures may increase the local concentration at specific sites resulting in location specific preferential solvation.

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