Metal-Free Ammonium Iodide Catalyzed Oxidative Dehydrocoupling of Silanes with Alcohols
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An ammonium iodide catalyzed direct oxidative coupling of silanes with alcohols to give various alkoxysilane derivatives was discovered. tert-Butyl hydroperoxide proved to be an efficient oxidant for this transformation. Attractive features of this protocol include its transition-metal-free nature and the mild reaction conditions.
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2016 ◽
Vol 358
(13)
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pp. 2035-2040
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2017 ◽
Vol 13
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pp. 1079-1084
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1973 ◽
Vol 95
(18)
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pp. 6136-6137
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