Stochastic Approach to First‐Order Chemical Reaction Kinetics

1966 ◽  
Vol 44 (3) ◽  
pp. 990-997 ◽  
Author(s):  
I. G. Darvey ◽  
P. J. Staff
1979 ◽  
Vol 44 (5) ◽  
pp. 1388-1396
Author(s):  
Václav Kolář ◽  
Zdeněk Brož

Relations describing the mass transfer accompanied by an irreversible first order chemical reaction are derived, based on the formerly published general theoretical concepts of interfacial mass transfer. These relations are compared with experimental results taken from literature.


1981 ◽  
Vol 18 (01) ◽  
pp. 263-267 ◽  
Author(s):  
F. D. J. Dunstan ◽  
J. F. Reynolds

Earlier stochastic analyses of chemical reactions have provided formal solutions which are unsuitable for most purposes in that they are expressed in terms of complex algebraic functions. Normal approximations are derived here for solutions to a variety of reactions. Using these, it is possible to investigate the level at which the classical deterministic solutions become inadequate. This is important in fields such as radioimmunoassay.


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