Crystal‐Field Spectra of d3,7 Ions. I. Electronic Absorption Spectrum of CoCl4= in Three Crystalline Environments

1963 ◽  
Vol 39 (1) ◽  
pp. 116-128 ◽  
Author(s):  
J. Ferguson
Keyword(s):  
Absorption Spectrum ◽  
Electronic Absorption Spectrum ◽  
Crystal Field ◽  
Electronic Absorption

The weak field representation of the crystal field matrices of d4,6 ions and the electronic absorption spectrum of RbFeF3

1969 ◽  
Vol 22 (9) ◽  
pp. 1809 ◽  
Author(s):  
J Ferguson ◽  
HJ Guggenheim ◽  
ER Krausz
Keyword(s):  
Absorption Spectrum ◽  
Electronic Absorption Spectrum ◽  
Crystal Field ◽  
Electronic Absorption ◽  
Strong Field ◽  
Weak Field ◽  
Triplet States ◽  
Spin Orbit ◽  
Crystal Field Theory ◽  
Field Representation

The electronic absorption spectrum of RbFeF3 is reported and analysed by means of crystal field theory. It is shown that the strong field formalism is limited for high spin Fe2+ and the weak field representation should be used to interpret the many triplet states. Published spin-orbit weak field matrices for d4,6 are shown to contain errors. The weak field matrices in the absence of spin-orbit coupling have been derived and they are used to assign the spectrum of RbFeF3.

Ortho effects on the change in electronic absorption spectrum of pyridinium salts of saturated bromohydrocarbon

2009 ◽  
Vol 74 (5) ◽  
pp. 1084-1089 ◽  
Author(s):  
Jin-Ling Song ◽  
Li-Ming Gong ◽  
Shou-Ai Feng ◽  
Jiang-Hong Zhao ◽  
Jian-Feng Zheng ◽  
...  
Keyword(s):  
Absorption Spectrum ◽  
Electronic Absorption Spectrum ◽  
Electronic Absorption ◽  
Pyridinium Salts

The electronic spectra of phenyl radicals

1965 ◽  
Vol 287 (1411) ◽  
pp. 457-470 ◽  
Keyword(s):  
Absorption Spectrum ◽  
Electronic Absorption Spectrum ◽  
Electronic Absorption ◽  
Ground State ◽  
Electronic Spectra ◽  
Flash Photolysis ◽  
Visible Region ◽  
Electronic Configuration ◽  
Vibrational Structure ◽  
Fundamental Frequencies

An electronic absorption spectrum, attributed to phenyl, has been observed in the visible region with origin at 18 908 cm -1 after flash photolysis of benzene and halogenobenzenes. Similar spectra of fluoro, chloro and bromo phenyl are observed after flash photolysis of disubstituted benzenes. The vibrational structure of the phenyl spectrum has been analysed in terms of two fundamental frequencies at 571 and 896 cm -1 which correspond to the e 2 g and a 1 g frequencies of the B 2 u state of benzene. The ground state of phenyl has a π 6 n electronic configuration and the observed transition is interpreted as 2 A 1 → 2 B 1 resulting from a π → n excitation.

The nature of the electronic absorption spectrum of 1, 3, 5-triphenylpyrazoline-?2

1971 ◽  
Vol 14 (2) ◽  
pp. 221-224 ◽  
Author(s):  
O. G. Korneeva ◽  
L. M. Kutsyna ◽  
V. G. Tishchenko
Keyword(s):  
Absorption Spectrum ◽  
Electronic Absorption Spectrum ◽  
Electronic Absorption
Sign in / Sign up

Export Citation Format

Share Document