Characterisation of H2S⋯CuCl and H2S⋯AgCl isolated in the gas phase: A rigidly pyramidal geometry at sulphur revealed by rotational spectroscopy and ab initio calculations

2011 ◽  
Vol 135 (1) ◽  
pp. 014307 ◽  
Author(s):  
Nicholas R. Walker ◽  
David P. Tew ◽  
Stephanie J. Harris ◽  
David E. Wheatley ◽  
Anthony C. Legon
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Gas Phase ◽  
Rotational Spectroscopy ◽  
Pyramidal Geometry

scholarly journals Gas phase complexes of H3N⋯CuF and H3N⋯CuI studied by rotational spectroscopy and ab initio calculations: the effect of X (X = F, Cl, Br, I) in OC⋯CuX and H3N⋯CuX

2016 ◽  
Vol 18 (19) ◽  
pp. 13638-13645 ◽  
Author(s):  
Dror M. Bittner ◽  
Susanna L. Stephens ◽  
Daniel P. Zaleski ◽  
David P. Tew ◽  
Nicholas R. Walker ◽  
...  
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Gas Phase ◽  
Microwave Spectroscopy ◽  
Rotational Spectroscopy

Complexes of H3N⋯CuF and H3N⋯CuI have been synthesised in the gas phase and characterized by microwave spectroscopy.

scholarly journals H3P⋯AgI: generation by laser-ablation and characterization by rotational spectroscopy and ab initio calculations

2016 ◽  
Vol 18 (28) ◽  
pp. 18971-18977 ◽  
Author(s):  
Susanna L. Stephens ◽  
David P. Tew ◽  
Nicholas R. Walker ◽  
Anthony C. Legon
Keyword(s):  
Laser Ablation ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Gas Phase ◽  
Rotational Spectroscopy ◽  
Dilute Mixture ◽  
Silver Metal

The new compound H3P⋯AgI has been synthesized in the gas phase by means of the reaction of laser-ablated silver metal with a pulse of gas consisting of a dilute mixture of ICF3 and PH3 in argon.

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