Catalytic conversion of ethene to butadiene or hydrogenation to ethane on HY zeolite-supported rhodium complexes: Cooperative support/Rh-center route

2021 ◽  
Vol 154 (18) ◽  
pp. 184706
Author(s):  
Konstantin Khivantsev ◽  
Artem Vityuk ◽  
Hristiyan A. Aleksandrov ◽  
Georgi N. Vayssilov ◽  
Oleg S. Alexeev ◽  
...  
Keyword(s):  
Catalytic Conversion ◽  
Rhodium Complexes ◽  
Hy Zeolite

Catalytic Conversion of 1,2,3-Trimethylbenzene Over HY Zeolite

1993 ◽  
Vol 40 (3) ◽  
pp. 221-227 ◽  
Author(s):  
An-Nan Ko ◽  
Ching Tung Kuo
Keyword(s):  
Catalytic Conversion ◽  
Hy Zeolite

Kinetics of catalytic conversion of methanol at higher pressures

1980 ◽  
Vol 45 (12) ◽  
pp. 3402-3407 ◽  
Author(s):  
Jaroslav Bartoň ◽  
Vladimír Pour
Keyword(s):  
Low Temperature ◽  
Reaction Kinetics ◽  
Water Vapour ◽  
Kinetic Data ◽  
Catalytic Conversion ◽  
The Given ◽  
Kinetics Of

The course of the conversion of methanol with water vapour was followed on a low-temperature Cu-Zn-Cr-Al catalyst at pressures of 0.2 and 0.6 MPa. The kinetic data were evaluated together with those obtained at 0.1 MPa and the following equation for the reaction kinetics at the given conditions was derived: r = [p(CH3OH)p(H2O)]0.5[p(H2)]-1.3.

Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

2006 ◽  
Vol 71 (2) ◽  
pp. 197-206 ◽  
Author(s):  
Martin Pošta ◽  
Jan Čermák ◽  
Pavel Vojtíšek ◽  
Ivana Císařová
Keyword(s):  
Rhodium Complexes ◽  
Iridium Complexes ◽  
X Ray ◽  
First Time

The first rhodium complexes of diphosphinoazines [{RhCl(1,2-η:5,6-η-CH=CHCH2CH2CH=CHCH2CH2)}2 {μ-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.

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