The ligand field spectra of trinuclear chromium(III) and iron(III) basic acetates
Keyword(s):
The visible spectra of trinuclear chromium(III) acetates [Cr3O(CH3CO2)6R2]+ can be successfully analysed by means of the ligand field theory for tetragonal fields. The ligands R (R = H2O, NH3, py, DMSO) are relatively labile and may be replaced by several ligands of varying donor strength. The spectra of trinuclear iron(III) acetates [Fe3O(CH3CO2)6R3]+ are poorly resolved but can be interpreted on the basis of a d5 configuration in octahedral fields.
1983 ◽
Vol 23
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pp. 169-183
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2015 ◽
Vol 622
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pp. 120-123
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1959 ◽
Vol 31
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pp. 1050-1061
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2013 ◽
Vol 428
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pp. 012023
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1967 ◽
Vol 71
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pp. 3155-3165
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1976 ◽
Vol 41
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pp. 3232-3244
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