Solvent Polarity Studies of the Water+t-Butyl Alcohol and Water+t-Butylamine Binary Systems With the Solvatochromic Dyes Nile Red and Pyridinium-N-phenoxide Betaine, Refractometry and Permittivity Measurements

1994 ◽  
Vol 47 (9) ◽  
pp. 1771 ◽  
Author(s):  
PK Kipkemboi ◽  
AJ Easteal

The empirical solvent polarity parameters ENR and ET for the solvatochromic compounds Nile Red (1) and pyridinium-N-phenoxide betaine (2), respectively, have been determined as a function of composition for water+t -butyl alcohol and water+t-butylamine binary mixtures, over the whole composition range at 298 K. For both systems the two parameters vary with composition in a strongly non-linear fashion, and the polarity of the mixture decreases with increasing proportion of the organic cosolvent. The non-linear variation of the polarity parameters is attributed to water-cosolvent hydrophobic interactions at low cosolvent contents, and hydrogen-bonding interactions at higher cosolvent contents. Permittivity and refractive index have also been measured at 298 K for both systems, and both properties are strongly non-linear functions of composition.

2005 ◽  
Vol 36 (4-5) ◽  
pp. 423-433 ◽  
Author(s):  
E. Jakobson ◽  
H. Ohvril ◽  
O. Okulov ◽  
N. Laulainen

The total mass of columnar water vapour (precipitable water, W) is an important parameter of atmospheric thermodynamic and radiative models. In this work more than 60 000 radiosonde observations from 17 aerological stations in the Baltic region over 14 years, 1989–2002, were used to examine the variability of precipitable water. A table of monthly and annual means of W for the stations is given. Seasonal means of W are expressed as linear functions of the geographical latitude degree. A linear formula is also derived for parametrisation of precipitable water as a function of two parameters – geographical latitude and surface water vapour pressure.


1976 ◽  
Vol 18 (1) ◽  
pp. 51-61
Author(s):  
Yasuhiro Kobayashi∗ ◽  
Masaaki Ohkita ◽  
Michio Inoue ◽  
Masao Nakamura
Keyword(s):  

2018 ◽  
Vol 616 ◽  
pp. A104 ◽  
Author(s):  
T. Kallinger ◽  
P. G. Beck ◽  
D. Stello ◽  
R. A. Garcia

Context. In recent years the global seismic scaling relations for the frequency of maximum power, νmax ∝ g / √Teff, and for the large frequency separation, Δν ∝ √ρ¯, have drawn attention in various fields of astrophysics. This is because these relations can be used to estimate parameters, such as the mass and radius of stars that show solar-like oscillations. With the exquisite photometry of Kepler, the uncertainties in the seismic observables are small enough to estimate masses and radii with a precision of only a few per cent. Even though this seems to work quite well for main-sequence stars, there is empirical evidence, mainly from studies of eclipsing binary systems, that the seismic scaling relations systematically overestimate the mass and radius of red giants by about 15% and 5%, respectively. Various model-based corrections of the Δν-scaling reduce the problem but do not solve it. Aims. Our goal is to define revised seismic scaling relations that account for the known systematic mass and radius discrepancies in a completely model-independent way. Methods. We use probabilistic methods to analyse the seismic data and to derive non-linear scaling relations based on a sample of six red giant branch (RGB) stars that are members of eclipsing binary systems and about 60 red giants on the RGB as well as in the core-helium burning red clump (RC) in the two open clusters NGC 6791 and NGC 6819. Results. We re-examine the global oscillation parameters of the giants in the binary systems in order to determine their seismic fundamental parameters and we find them to agree with the dynamic parameters from the literature if we adopt non-linear scalings. We note that a curvature and glitch corrected Δνcor should be preferred over a local or average value of Δν. We then compare the observed seismic parameters of the cluster giants to those scaled from independent measurements and find the same non-linear behaviour as for the eclipsing binaries. Our final proposed scaling relations are based on both samples and cover a broad range of evolutionary stages from RGB to RC stars: g / √Teff = (νmax / νmax,⊙)1.0075±0.0021 and √ρ¯ = (Δνcor / Δνcor,⊙)[η − (0.0085 ± 0.0025) log2(Δνcor / Δνcor,⊙)]−1, where g, Teff, and ρ¯ are in solar units, νmax,⊙ = 3140 ± 5 μHz and Δνcor,⊙ = 135.08 ± 0.02 μHz, and η is equal to one in the case of RGB stars and 1.04 ± 0.01 for RC stars. Conclusions. A direct consequence of these new scaling relations is that the average mass of stars on the ascending giant branch reduces to 1.10 ± 0.03 M⊙ in NGC 6791 and 1.45 ± 0.06 M⊙ in NGC 6819, allowing us to revise the clusters’ distance modulus to 13.11 ± 0.03 and 11.91 ± 0.03 mag, respectively. We also find strong evidence that both clusters are significantly older than concluded from previous seismic investigations.


2021 ◽  
Vol 10 (6) ◽  
Author(s):  
Matthias Bartelmann ◽  
Johannes Dombrowski ◽  
Sara Konrad ◽  
Elena Kozlikin ◽  
Robert Lilow ◽  
...  

We use the recently developed Kinetic Field Theory (KFT) for cosmic structure formation to show how non-linear power spectra for cosmic density fluctuations can be calculated in a mean-field approximation to the particle interactions. Our main result is a simple, closed and analytic, approximate expression for this power spectrum. This expression has two parameters characterising non-linear structure growth which can be calibrated within KFT itself. Using this self-calibration, the non-linear power spectrum agrees with results obtained from numerical simulations to within typically \lesssim10\,\%≲10% up to wave numbers k\lesssim10\,h\,\mathrm{Mpc}^{-1}k≲10hMpc−1 at redshift z = 0z=0. Adjusting the two parameters to optimise agreement with numerical simulations, the relative difference to numerical results shrinks to typically \lesssim 5\,\%≲5%. As part of the derivation of our mean-field approximation, we show that the effective interaction potential between dark-matter particles relative to Zel’dovich trajectories is sourced by non-linear cosmic density fluctuations only, and is approximately of Yukawa rather than Newtonian shape.


2020 ◽  
Vol 14 (10) ◽  
pp. 1387-1392
Author(s):  
Marlen Meza-Sánchez ◽  
Maria del Carmen Rodríguez-Liñán ◽  
Eddie Clemente

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