Spectroscopic probing and diagnostics of the geometric structure of the alkoxy and alkyl peroxy radical intermediates

2006 ◽  
Vol 104 (16-17) ◽  
pp. 2581-2593 ◽  
Author(s):  
Terry A. Miller
Keyword(s):  
Geometric Structure ◽  
Peroxy Radical ◽  
Radical Intermediates ◽  
Alkyl Peroxy Radical

scholarly journals Isolation and Characterization of Alkyl Peroxy Radical Scavenging Compound from Leaves of Laurus nobilis

2002 ◽  
Vol 25 (1) ◽  
pp. 102-108 ◽  
Author(s):  
Hye Won Kang ◽  
Kwang Won Yu ◽  
Woo Jin Jun ◽  
Ih Seop Chang ◽  
Sang Bae Han ◽  
...  
Keyword(s):  
Radical Scavenging ◽  
Peroxy Radical ◽  
Laurus Nobilis ◽  
Isolation And Characterization ◽  
Alkyl Peroxy Radical

Radical products of hydroxylamines, nitrones and spin adducts in the process of gradual oxidation with coordinated peroxy-radicals

1981 ◽  
Vol 46 (4) ◽  
pp. 823-832 ◽  
Author(s):  
Vlado Cholvad ◽  
Andrej Staško ◽  
Alexander Tkáč ◽  
Anatolii L. Buchanenko ◽  
L'ubomír Malík
Keyword(s):  
Peroxy Radical ◽  
Epr Spectra ◽  
Spin Adduct ◽  
Peroxy Radicals ◽  
Carbonyl Groups ◽  
Radical Intermediates

Hydroxyperoxides and cobalt-coordinated peroxy-radicals oxidize hydroxyolamines as e.g. Et2NOH, (PhCH2)2NOH, PhCH2PhNOH to the respective nitrones, and the spin adducts - nitrone and peroxy-radical - are formed. In contrast to hydroxyperoxides the coordinated peroxy radicals can oxidize the formed spin adduct, the methylene or methine groups next to nitrogen being converted into carbonyl groups. The radical intermediates corresponding to individual steps of the gradual oxidation have been identified by means of EPR spectra.

Role of zeolite encapsulated Cu(II) complexes in electron transfer as well as peroxy radical intermediates formation during oxidation of thioanisole

2020 ◽  
Vol 389 ◽  
pp. 305-316 ◽  
Author(s):  
Bidyut Kumar Kundu ◽  
Mriganka Das ◽  
Rakesh Ganguly ◽  
Preeti A. Bhobe ◽  
Suman Mukhopadhyay
Keyword(s):  
Electron Transfer ◽  
Peroxy Radical ◽  
Radical Intermediates

High-Pressure Rate Rules for Alkyl + O2Reactions. 1. The Dissociation, Concerted Elimination, and Isomerization Channels of the Alkyl Peroxy Radical

2011 ◽  
Vol 115 (46) ◽  
pp. 13425-13442 ◽  
Author(s):  
Stephanie M. Villano ◽  
Lam K. Huynh ◽  
Hans-Heinrich Carstensen ◽  
Anthony M. Dean
Keyword(s):  
High Pressure ◽  
Peroxy Radical ◽  
Alkyl Peroxy Radical

The geometric structure and optical response of gaseous endohedral magnesium-fullerenes

2003 ◽  
Vol 50 (15-17) ◽  
pp. 2691-2704 ◽  
Author(s):  
M. Aichinger ◽  
S. A. Chin ◽  
E. Krotscheck ◽  
H. A. Schuessler
Keyword(s):  
Geometric Structure ◽  
Optical Response

Visible Light-Promoted Catalytic Ring-Opening Isomerization of 1,2-Disubstituted Cyclopropanols to Linear Ketones

2019 ◽  
Author(s):  
Marharyta V. Laktsevich-Iskryk ◽  
Nastassia A. Varabyeva ◽  
Volha V. Kazlova ◽  
Vladimir N. Zhabinskii ◽  
Vladimir A. Khripach ◽  
...  
Keyword(s):  
Visible Light ◽  
Functional Groups ◽  
Ring Opening ◽  
Radical Intermediates ◽  
Reaction Proceeds

In this article, we report a photocatalytic protocol for the isomerization of 1,2-disubstituted cyclopropanols to linear ketones. The reaction proceeds <i>via</i> radical intermediates and tolerates various functional groups.

Visible Light-Promoted Catalytic Ring-Opening Isomerization of 1,2-Disubstituted Cyclopropanols to Linear Ketones

2019 ◽  
Author(s):  
Marharyta V. Laktsevich-Iskryk ◽  
Nastassia A. Varabyeva ◽  
Volha V. Kazlova ◽  
Vladimir N. Zhabinskii ◽  
Vladimir A. Khripach ◽  
...  
Keyword(s):  
Visible Light ◽  
Functional Groups ◽  
Ring Opening ◽  
Radical Intermediates ◽  
Reaction Proceeds

In this article, we report a photocatalytic protocol for the isomerization of 1,2-disubstituted cyclopropanols to linear ketones. The reaction proceeds <i>via</i> radical intermediates and tolerates various functional groups.

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