scholarly journals Analysis on Electrochemical Impedance Data Based on Computer Fitting

2021 ◽  
Vol 1992 (2) ◽  
pp. 022149
Author(s):  
Yu Zhang
Keyword(s):  
Electrochemical Impedance ◽  
Impedance Data

A Bayesian View on the Hilbert Transform and the Kramers-Kronig Transform of Electrochemical Impedance Data: Probabilistic Estimates and Quality Scores

2020 ◽  
Author(s):  
Jiapeng Liu ◽  
Ting Hei Wan ◽  
Francesco Ciucci
Keyword(s):  
Power Generation ◽  
Electrochemical Impedance Spectroscopy ◽  
Hilbert Transform ◽  
Electrochemical Impedance ◽  
The Self ◽  
Impedance Data ◽  
The Hilbert Transform ◽  
Validation Tests ◽  
Self Consistency ◽  
Mathematical Relations

<p>Electrochemical impedance spectroscopy (EIS) is one of the most widely used experimental tools in electrochemistry and has applications ranging from energy storage and power generation to medicine. Considering the broad applicability of the EIS technique, it is critical to validate the EIS data against the Hilbert transform (HT) or, equivalently, the Kramers–Kronig relations. These mathematical relations allow one to assess the self-consistency of obtained spectra. However, the use of validation tests is still uncommon. In the present article, we aim at bridging this gap by reformulating the HT under a Bayesian framework. In particular, we developed the Bayesian Hilbert transform (BHT) method that interprets the HT probabilistic. Leveraging the BHT, we proposed several scores that provide quick metrics for the evaluation of the EIS data quality.<br></p>

Applications of Kramers—Kronig transforms in the analysis of electrochemical impedance data—III. Stability and linearity

1990 ◽  
Vol 35 (10) ◽  
pp. 1559-1566 ◽  
Author(s):  
Mirna Urquidi-Macdonald ◽  
Silvia Real ◽  
Digby D. Macdonald
Keyword(s):  
Electrochemical Impedance ◽  
Impedance Data

scholarly journals An Electrochemical Impedance Study of AISI 321 Stainless Steel in 0.5 M H2SO4

2011 ◽  
Vol 2011 ◽  
pp. 1-10
Author(s):  
A. Fattah-Alhosseini ◽  
M. Mosavi ◽  
A. Allahdadi
Keyword(s):  
Stainless Steel ◽  
Polarization Resistance ◽  
Electrochemical Impedance ◽  
Electrical Circuit ◽  
Defect Model ◽  
Impedance Data ◽  
Resistance Decrease ◽  
Aisi 321 ◽  
Equivalent Electrical Circuit Model ◽  
Interfacial Impedance

The electrochemical behavior of passive films formed on AISI 321 has been examined using electrochemical impedance spectroscopy. AISI 321 is characterized by high interfacial impedance, thereby illustrating its high corrosion resistance. Results showed that the interfacial impedance and the polarization resistance initially increase with applied potential, within the low potential. However, at a sufficiently high potential ( V), the interfacial impedance and the polarization resistance decrease with increasing potential. The impedance data were adequately represented by an equivalent electrical circuit model based on point defect model, which described the behavior of the passive film on stainless steel more satisfactorily than the proposed models.

scholarly journals A Bayesian View on the Hilbert Transform and the Kramers-Kronig Transform of Electrochemical Impedance Data: Probabilistic Estimates and Quality Scores

2020 ◽  
Author(s):  
Jiapeng Liu ◽  
Ting Hei Wan ◽  
Francesco Ciucci
Keyword(s):  
Power Generation ◽  
Electrochemical Impedance Spectroscopy ◽  
Hilbert Transform ◽  
Electrochemical Impedance ◽  
The Self ◽  
Impedance Data ◽  
The Hilbert Transform ◽  
Validation Tests ◽  
Self Consistency ◽  
Mathematical Relations

<p>Electrochemical impedance spectroscopy (EIS) is one of the most widely used experimental tools in electrochemistry and has applications ranging from energy storage and power generation to medicine. Considering the broad applicability of the EIS technique, it is critical to validate the EIS data against the Hilbert transform (HT) or, equivalently, the Kramers–Kronig relations. These mathematical relations allow one to assess the self-consistency of obtained spectra. However, the use of validation tests is still uncommon. In the present article, we aim at bridging this gap by reformulating the HT under a Bayesian framework. In particular, we developed the Bayesian Hilbert transform (BHT) method that interprets the HT probabilistic. Leveraging the BHT, we proposed several scores that provide quick metrics for the evaluation of the EIS data quality.<br></p>

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