4. Types and hexagons

Author(s):  
William H. Brock

‘Types and hexagons’ introduces some of the key characters involved in making important contributions to the field of chemistry: Antoine Fourcroy, who created the divisions of inorganic and organic chemistry; Friedrich Kekulé, who defined organic chemistry as the chemistry of carbon compounds and proposed benzene’s hexagonal structure; Justus Liebig, who applied chemistry to agriculture, physiology, medicine, nutrition, and industry; Berzelius, who introduced the term isomerism and the electrochemical system of classification; French chemists Charles Gerhardt and August Laurent; Edward Frankland, who proposed valency; Alfred Werner and his coordination theory of molecular structure; and Alexander Williamson, who had a pivotal role in the development of 19th-century chemistry.

1970 ◽  
Vol 24 (6) ◽  
pp. 591-595 ◽  
Author(s):  
D. W. Mayo ◽  
Stanley K. Freeman

The use of Raman spectroscopy in the determination of complex molecular structure is discussed. For 12 cedranes, five of the seven most intense bands observed between 900 and 500 cm−1 appear in a series of relatively narrow wavenumber ranges, and these are correctable with the cedrane skeleton. A band of variable intensity at ca. 320 cm−1, characterized by a ρ value of 0.2–0.4, may be included in the correlation pattern.


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