Role of the surface electronic response function on treatments of the liquid-vapor interface of alkali metals

1994 ◽  
Vol 49 (16) ◽  
pp. 11405-11408 ◽  
Author(s):  
M. A. Gómez ◽  
E. Chacón
Keyword(s):  
Response Function ◽  
Alkali Metals ◽  
Vapor Interface ◽  
Electronic Response ◽  
Liquid Vapor

A Numerical Description of a Liquid-Vapor Interface Based on the Second Gradient Theory

1995 ◽  
Vol 22 (1) ◽  
pp. 1-14 ◽  
Author(s):  
Didier Jamet ◽  
Olivier Lebaigue ◽  
Jean-Marc Delhaye ◽  
N. Coutris
Keyword(s):  
Gradient Theory ◽  
Vapor Interface ◽  
Second Gradient ◽  
Liquid Vapor

Cation-Induced Dimerization of Crown-Substituted Gallium Phthalocyanine by Complexing with Alkali Metals: The Crucial Role of a Central Metal

2021 ◽  
Vol 60 (3) ◽  
pp. 1948-1956
Author(s):  
Lyudmila A. Lapkina ◽  
Anna A. Sinelshchikova ◽  
Kirill P. Birin ◽  
Vladimir E. Larchenko ◽  
Mikhail S. Grigoriev ◽  
...  
Keyword(s):  
Crucial Role ◽  
Alkali Metals ◽  
Central Metal

scholarly journals Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides

Crystals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1013
Author(s):  
Stefanie Gärtner
Keyword(s):  
Crystal Structure ◽  
Alkali Metal ◽  
Crystal Structures ◽  
Alkali Metals ◽  
Valence Electron ◽  
Oxidation States ◽  
Valence Electron Concentration ◽  
Base Metals ◽  
Charge Balancing

Alkali metal thallides go back to the investigative works of Eduard Zintl about base metals in negative oxidation states. In 1932, he described the crystal structure of NaTl as the first representative for this class of compounds. Since then, a bunch of versatile crystal structures has been reported for thallium as electronegative element in intermetallic solid state compounds. For combinations of thallium with alkali metals as electropositive counterparts, a broad range of different unique structure types has been observed. Interestingly, various thallium substructures at the same or very similar valence electron concentration (VEC) are obtained. This in return emphasizes that the role of the alkali metals on structure formation goes far beyond ancillary filling atoms, which are present only due to charge balancing reasons. In this review, the alkali metals are in focus and the local surroundings of the latter are discussed in terms of their crystallographic sites in the corresponding crystal structures.

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